1,3,2-Dioxaphosphorinane, 2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(oxy)]bis[5,5-dimethyl-

Base Information

• Chemical Name: 1,3,2-Dioxaphosphorinane, 2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(oxy)]bis[5,5-dimethyl-
• CAS No.: 59609-05-1
• Molecular Formula: C15H30 O6 P2
• Molecular Weight: 368.347
• European Community (EC) Number: 261-824-6
• DSSTox Substance ID: DTXSID9069340
• Nikkaji Number: J298.191B
• Wikidata: Q81996195
• Mol file: 59609-05-1.mol

Synonyms:59609-05-1;EINECS 261-824-6;1,3,2-Dioxaphosphorinane, 2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(oxy)]bis[5,5-dimethyl-;1,3,2-Dioxaphosphorinane, 2,2'-((2,2-dimethyl-1,3-propanediyl)bis(oxy))bis(5,5-dimethyl-;2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(oxy)]bis[5,5-dimethyl-1,3,2-dioxaphosphorinane];2,2'-((2,2-Dimethylpropane-1,3-diyl)bis(oxy))bis(5,5-dimethyl-1,3,2-dioxaphosphorinane);SCHEMBL4923893;DTXSID9069340;C15H30O6P2;C15-H30-O6-P2;1,3-Propanediol, 2,2-dimethyl-, bis(cyclic 2,2-dimethyltrimethylene phosphite);2,2'-[(2,2-Dimethyl-1,3-propanediyl)bis(oxy)]bis(5,5-dimethyl-1,3,2-dioxaphosphorinane)

Chemical Property of 1,3,2-Dioxaphosphorinane, 2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(oxy)]bis[5,5-dimethyl-

Chemical Property:

• Boiling Point: 366.7oC at 760 mmHg
• Flash Point: 216oC
• PSA: 82.56000
• LogP: 4.64560
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 368.15176267
• Heavy Atom Count: 23
• Complexity: 334

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(COP(OC1)OCC(C)(C)COP2OCC(CO2)(C)C)C

Technology Process of 1,3,2-Dioxaphosphorinane, 2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(oxy)]bis[5,5-dimethyl-

There total 12 articles about 1,3,2-Dioxaphosphorinane, 2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(oxy)]bis[5,5-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.1%

C20H39O9P3 → 2,2'-(2,2-dimethyl-1,3-propanedioxy)-5,5-dimethyl-1,3,2-dioxaphosphorinane-5',5'-dimethyl-1',3',2'-dioxaphosphorinane (59609-05-1) + 4-methyl-2,6,7-trioxa-1-phosphabicyclo-[2,2,2]-octane (1449-91-8)

Guidance literature:

at 100 - 105 ℃; for 16h; under 1 Torr;

Reference yield: 96.0%

N,N'-Bis-(5,5-dimethyl-[1,3,2]dioxaphosphinan-2-yl)-2-{[(5,5-dimethyl-[1,3,2]dioxaphosphinan-2-yl)-methyl-amino]-methyl}-2,N,N'-trimethyl-propane-1,3-diamine → 2,2'-(2,2-dimethyl-1,3-propanedioxy)-5,5-dimethyl-1,3,2-dioxaphosphorinane-5',5'-dimethyl-1',3',2'-dioxaphosphorinane (59609-05-1) + 2,6,7-trimethyl-4-methyl-2,6,7-triaza-1-phosphaicyclo<2.2.2>octane (14418-26-9)

Guidance literature:

at 110 ℃; for 1h; under 25 Torr;

Reference yield:

2-chloro-5,5-dimethyl-[1,3,2]dioxaphosphinane (2428-06-0) → 2,2'-(2,2-dimethyl-1,3-propanedioxy)-5,5-dimethyl-1,3,2-dioxaphosphorinane-5',5'-dimethyl-1',3',2'-dioxaphosphorinane (59609-05-1)

Guidance literature:

With sodium; In xylene; at 110 ℃; further reagents (Li, K); other solvents (HMPT, THF);

upstream raw materials:

2,2-Dimethyl-1,3-propanediol

1-fluoro-4,4-dimethyl-1-phospha-2,6-dioxacyclohexane

2-chloro-5,5-dimethyl-[1,3,2]dioxaphosphinane

diethylamine

Downstream raw materials:

((CH₃)2C(CH₂OP(OCH₂)2C(CH₃)2)2)Ni(P(C₆H₁₁-cyclo)3)2