1,1a(2)-Bis(tributylstannyl)ferrocene

Base Information

Chemical Name:1,1a(2)-Bis(tributylstannyl)ferrocene
CAS No.:12291-11-1
Molecular Formula:C34H62 Fe Sn2
Molecular Weight:764.133
Hs Code.:
DSSTox Substance ID:DTXSID101298344

Synonyms:DTXSID101298344;1,1a(2)-Bis(tributylstannyl)ferrocene

Suppliers and Price of 1,1a(2)-Bis(tributylstannyl)ferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 4 raw suppliers

Chemical Property of 1,1a(2)-Bis(tributylstannyl)ferrocene

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:20
Exact Mass:774.30215
Heavy Atom Count:37
Complexity:172

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C1CCCC1.CCCC[Sn](CCCC)(CCCC)C1CCCC1.[Fe]

Technology Process of 1,1a(2)-Bis(tributylstannyl)ferrocene

There total 1 articles about 1,1a(2)-Bis(tributylstannyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1,1'-dilithioferrocene N,N,N'N'-tetramethylethylenediamine

: 1461-22-9
tributyltin chloride

: 102-54-5,55404-68-7
ferrocene

: tri-n-butylstannylferrocene

: 12291-11-1
1,1'-bis(tri-n-butylstannyl)ferrocene

Guidance literature:: In diethyl ether; addn. of Bu3SnCl to Fe complex in ether (0°C), warming to ambient temp. (6 h); washing (water, brine), drying org. layer (K2CO3), solvent removal, chromy. (alumina, pentane), collection, solvent removal;
DOI:10.1021/om00117a049

Reference yield: 94.0%

: 12291-11-1
1,1'-bis(tri-n-butylstannyl)ferrocene

: 882-33-7
diphenyldisulfane

: 1-(tri-n-butylstannyl)-1'-(phenylthio)ferrocene

Guidance literature:: With n-BuLi; In tetrahydrofuran; under N2; dropwise addn. of n-BuLi to soln. of complex at -78°C, stirred for 30 min, addn. of PhSSPh in THF; cooling bath removed, mixture diluted with ether, washed (H2O, brine), organic layer dried, evapd. (vac.), residue chromd. (Al2O3, hexane), second band collected;

Reference yield: 93.0%

: 12291-11-1
1,1'-bis(tri-n-butylstannyl)ferrocene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 124944-39-4
1-(tri-n-butylstannyl)-1'-(diphenylphosphino)ferrocene

Guidance literature:: With n-butyllithium; In tetrahydrofuran; addn. of n-BuLi to Fe-complex in THF (-78°C), stirring (30 min), addn. of org. compd.; addn. of ether, washing (water, brine), drying org. layer, solvent removal (reduced pressure), chromy. (alumina, hexane), collection, solvent removal; elem. anal.;
DOI:10.1021/om00117a049