Methyl 2,6-dideoxy-3,4-bis-o-[(4-methylphenyl)sulfonyl]hexopyranoside

Base Information

Chemical Name:Methyl 2,6-dideoxy-3,4-bis-o-[(4-methylphenyl)sulfonyl]hexopyranoside
CAS No.:67758-43-4
Molecular Formula:C21H26O8S2
Molecular Weight:470.5563
Hs Code.:
NSC Number:108085
DSSTox Substance ID:DTXSID60296169

Synonyms:67758-43-4;NSC108085;methyl 2,6-dideoxy-3,4-bis-o-[(4-methylphenyl)sulfonyl]hexopyranoside;DTXSID60296169;NSC-108085

Suppliers and Price of Methyl 2,6-dideoxy-3,4-bis-o-[(4-methylphenyl)sulfonyl]hexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Methyl 2,6-dideoxy-3,4-bis-o-[(4-methylphenyl)sulfonyl]hexopyranoside

Chemical Property:

Vapor Pressure:1.67E-14mmHg at 25°C
Boiling Point:617.2°Cat760mmHg
Flash Point:327.1°C
Density:1.37g/cm³
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:7
Exact Mass:470.10691013
Heavy Atom Count:31
Complexity:769

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1C(C(CC(O1)OC)OS(=O)(=O)C2=CC=C(C=C2)C)OS(=O)(=O)C3=CC=C(C=C3)C

Technology Process of Methyl 2,6-dideoxy-3,4-bis-o-[(4-methylphenyl)sulfonyl]hexopyranoside

There total 14 articles about Methyl 2,6-dideoxy-3,4-bis-o-[(4-methylphenyl)sulfonyl]hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 19131-10-3
methyl-2,6-didesoxy-α-L-arabino-hexopyranoside

: 98-59-9
p-toluenesulfonyl chloride

: 67758-44-5
Methyl 2,6-dideoxy-α-L-arabino-hexopyranoside 4-p-toluenesulfonate

: 18981-61-8
Methyl 2,6-dideoxy-α-L-arabino-hexopyranoside 3-p-toluenesulfonate

: 67758-43-4
Methyl 2,6-dideoxy-α-L-arabino-hexopyranoside 3,4-di-p-toluenesulfonate

Guidance literature:: With pyridine; refrigerator, overnight;
DOI:10.1021/jo00174a028

Reference yield:

: 87858-15-9
3,4,5,6-Tetra-O-acetyl-1,2-dideoxy-1-nitro-L-arabino-hexitol

: 67758-43-4
Methyl 2,6-dideoxy-α-L-arabino-hexopyranoside 3,4-di-p-toluenesulfonate

Guidance literature:: Multi-step reaction with 4 steps

1: 1) Ba(OH)2*8H₂O, 2) H₂SO₄ / 1) water, room temp., 2) <10 degC -> room temp., overnight

2: AG 50-X₄(H⁺) / 120 h / Ambient temperature

4: 16 percent / pyridine / refrigerator, overnight

With pyridine; barium dihydroxide; AG 50-X₄(H⁺); sulfuric acid;
DOI:10.1021/jo00174a028

Reference yield:

: 87858-14-8
3,4,5,6-Tetra-O-acetyl-1,2-dideoxy-1-nitro-L-arabino-hex-1-enitol

: 67758-43-4
Methyl 2,6-dideoxy-α-L-arabino-hexopyranoside 3,4-di-p-toluenesulfonate

Guidance literature:: Multi-step reaction with 5 steps

1: 78 percent / H₂ / 10percent Pd/C / ethyl acetate / Ambient temperature

2: 1) Ba(OH)2*8H₂O, 2) H₂SO₄ / 1) water, room temp., 2) <10 degC -> room temp., overnight

3: AG 50-X₄(H⁺) / 120 h / Ambient temperature

5: 16 percent / pyridine / refrigerator, overnight

With pyridine; barium dihydroxide; AG 50-X₄(H⁺); sulfuric acid; hydrogen; palladium on activated charcoal; In ethyl acetate;
DOI:10.1021/jo00174a028