19131-10-3

Basic information

• Product Name: methyl 2,6-dideoxyhexopyranoside
• Synonyms: Methyl 2,6-dideoxyhexopyranoside
• CAS NO: 19131-10-3
• Molecular Formula: C₇H₁₄O₄
• Molecular Weight: 162.1837
• Mol File: 19131-10-3.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 273.7°C at 760 mmHg
• Flash Point: 119.3°C
• Density: 1.19g/cm³
• Vapor Pressure: 0.000722mmHg at 25°C
• Refractive Index: 1.482
• CAS DataBase Reference: methyl 2,6-dideoxyhexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,6-dideoxyhexopyranoside(19131-10-3)
• EPA Substance Registry System: methyl 2,6-dideoxyhexopyranoside(19131-10-3)

Safety Data

• Hazardous Substances Data: 19131-10-3(Hazardous Substances Data)

Upstream product

• 83497-33-0 methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside 
• 67-56-1 methanol 
• 2053-00-1 D-digitoxose 
• 51020-42-9 2-deoxy-α-L-fucopyranose 
• 25029-50-9 2,6-dideoxy-α-L-arabino-hexose 
• 3615-37-0 D-Fucose 
• 18742-02-4 2-bromo-2-(2-ethyl)dioxolane 
• 78464-95-6 methyl 3,4-di-O-acetyl-2,6-dideoxy-α-L-lyxo-hexopyranoside 
• 139656-45-4 methyl 2,6-dideoxy-3,4-bis-O-<(trifluoromethyl)sulfonyl>-β-D-ribo-hexopyranoside 
• 139756-72-2 methyl 2,6-dideoxy-β-D-lyxo-hexopyranoside 
• 141208-33-5 Methyl 2,6-dideoxy-3,4-di-O-trifluoromethylsulfonyl-β-D-lyxo-hexopyranoside 
• 62131-22-0 2,3-anhydro-6-bromo-6-deoxy-1-O-methyl-α-D-allopyranoside 
• 18933-59-0 2,3-anhydro-4-O-benzoyl-6-bromo-6-deoxy-1-O-methyl-α-D-allopyranoside 
• 66537-92-6 methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside 

Downstream Products

• 67758-44-5 Methyl 2,6-dideoxy-α-L-arabino-hexopyranoside 4-p-toluenesulfonate 
• 151960-58-6 ((2S,3R,4S,6R)-4-Benzyloxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl)-dimethyl-amine 
• 151960-57-5 (2S,3R,4S,6R)-3-Azido-4-benzyloxy-6-methoxy-2-methyl-tetrahydro-pyran 
• 151960-56-4 Toluene-4-sulfonic acid (2S,3S,4S,6R)-4-benzyloxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 18977-92-9 methyl α-L-daunosaminide 
• 54623-23-3 methyl-3-amino-2,3,6-tridesoxy-α-L-arabino-hexopyranoside 
• 54623-22-2 methyl-3-azido-2,3,6-tridesoxy-α-L-arabino-hexopyranoside 
• 18981-62-9 methyl 3-azido-2,3,6-trideoxy-4-O-methanesulphonyl-α-L-arabino-hexopyranoside 
• 85439-70-9 methyl-3,4-anhydro-2,6-didesoxy-α-L-lyxo-hexopyranoside 
• 18981-64-1 Methyl 3-azido-2,3,6-trideoxy-α-L-lyxo-hexopyranoside 
• 139190-82-2 (3aR,4R,6R,7aS)-6-Cyclohexylmethoxy-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 139190-81-1 (3aR,4R,6S,7aS)-6-Cyclohexylmethoxy-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 141805-54-1 (2R,3S,4S)-2-Methyl-6-phenylsulfanyl-tetrahydro-pyran-3,4-diol 
• 139190-72-0 (3aR,4R,7aS)-2,2,4-Trimethyl-6-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 

Relevant articles and documents

A Change from Kinetic to Thermodynamic Control Enables trans-Selective Stereochemical Editing of Vicinal Diols

Here, we report the selective, catalytic isomerization of cis-1,2-diols to trans-diequatorial-1,2-diols. The method employs triphenylsilanethiol (Ph3SiSH) as a catalyst and proceeds under mild conditions in the presence of a photoredox catalyst and under

Synthesis of ribo-hexopyranoside- and altrose-based azacrown ethers and their application in an asymmetric Michael addition

The synthesis of four new ribo-hexopyranoside-based chiral lariat ethers of monoaza-15-crown-5 type and two altropyranoside-based crown ethers were elaborated. Our syntheses utilized the regioselective ring opening of the oxiran moiety of the 2,3-anhydro sugars by nucleophilic reagents to afford the key intermediates. The reaction of methyl-2,3-anhydro-4,6-O-benzylidene-α-d- mannopyranoside with ethanolamine is especially of interest to afford a 3-substituted altropyranoside. One of the ribo-hexopyranoside-based lariat ethers with a 4-methoxyphenyl substituent induced an enantioselectivity of 80% when used as catalyst in the Michael addition of diethyl acetamidomalonate to trans-β-nitrostyrene under phase transfer catalytic conditions.

Halichoblelides B and C, potent cytotoxic macrolides from a Streptomyces species separated from a marine fish

Halichoblelide B (1) and C (2), novel macrolides with potent cytotoxicity against tumor cells in culture, have been isolated from a strain of Streptomyces hygroscopicus originally derived from the marine fish Halichoeres bleekeri, and their absolute stereostructures have been elucidated on the basis of spectroscopic analyses using 1D and 2D NMR techniques and chemical transformations. These compounds exhibited significant cytotoxicity against human cancer cell lines.