Tetrabutylammonium dicarbonyldichlororhodate

Base Information

• Chemical Name: Tetrabutylammonium dicarbonyldichlororhodate
• CAS No.: 14593-70-5
• Molecular Formula: C₂Cl₂O₂Rh*C₁₆H₃₆N
• Molecular Weight: 472.301
• Mol file: 14593-70-5.mol

Synonyms:tetrabutylammonium dicarbonyldichlororhodate;Tetrabutylammonium dichlorodicarbonylrhodium

Chemical Property of Tetrabutylammonium dicarbonyldichlororhodate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tetrabutylammonium dicarbonyldichlororhodate

There total 4 articles about Tetrabutylammonium dicarbonyldichlororhodate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetra-n-butylammonium dicarbonyldiiodorhodate(I) (30192-00-8,13927-74-7) → {NBu4}{Rh(CO)2Cl2} (17966-76-6,14593-70-5)

Guidance literature:

With Cl^(1-); In chloroform; byproducts: I(1-);

DOI:10.1016/0022-328X(91)80168-J

Reference yield:

tetrabutylammonium acetate (10534-59-5) → {NBu4}{Rh(CO)2Cl2} (17966-76-6,14593-70-5)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: Cl^(1-) / chloroform

With Cl^(1-); In tetrahydrofuran; chloroform;

DOI:10.1016/0022-328X(91)80168-J

Reference yield:

di(rhodium)tetracarbonyl dichloride + tetrabutyl-ammonium chloride (1112-67-0) → {NBu4}{Rh(CO)2Cl2} (17966-76-6,14593-70-5)

Guidance literature:

In methanol; under nitrogen; filtn., removal of the solvent, crystn. at 0°C, elem. anal.;

DOI:10.1016/0022-328X(91)80168-J

upstream raw materials:

(Cl₂Rh(CO))^(1-)

carbon monoxide

tetrabutyl-ammonium chloride

tetra-n-butylammonium dicarbonyldiiodorhodate(I)

Downstream raw materials:

P-trans-Br{Rh(o-diphenylphosphinophenylamine)(CO)Br}

P-trans-I{Rh(o-diphenylphosphinophenylamine)(CO)I}

P-trans-Cl{Rh(o-diphenylphosphinophenylamine)(CO)Cl}

(N,N'-bis{2-(diphenylphosphino)phenyl}propane-1,3-diamine)carbonylchlororhodium(I)

Refernces

• 1、 Fulford, Anthony,Bailey, Neil A.,Adams, Harry,Maitlis, Peter M.. "The synthesis, properties, and crystal structure of n-Bu4N, and the exchange of acetate, chloride, and iodide in n-Bu4N". . p. 139 - 147. Retrieved 2007/10/02.