N-Nitroso-2,6-dimethylmorpholine

Base Information

• Chemical Name: N-Nitroso-2,6-dimethylmorpholine
• CAS No.: 1456-28-6
• Molecular Formula: C₆H₁₂N₂O₂
• Molecular Weight: 144.173
• NSC Number: 69924
• DSSTox Substance ID: DTXSID4021470
• Nikkaji Number: J3.367G
• ChEMBL ID: CHEMBL164456
• Mol file: 1456-28-6.mol

Synonyms:dimethylnitrosomorpholine;N-nitroso-2,6-dimethylmorpholine;N-nitroso-2,6-dimethylmorpholine, (cis)-isomer;N-nitroso-2,6-dimethylmorpholine, (trans)-isomer

Chemical Property of N-Nitroso-2,6-dimethylmorpholine

Chemical Property:

• Vapor Pressure: 0.0933mmHg at 25°C
• Refractive Index: 1.4500 (estimate)
• Boiling Point: 231.7°C at 760 mmHg
• Flash Point: 93.9°C
• PSA: 41.90000
• Density: 1.22g/cm³
• LogP: 0.71490
• Water Solubility.: 124g/L(24 oC)
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 144.089877630
• Heavy Atom Count: 10
• Complexity: 119

Purity/Quality:

99% ^*data from raw suppliers

N-NITROSO-2,6-DIMETHYLMORPHOLINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Nitrosamines
• Canonical SMILES: CC1CN(CC(O1)C)N=O

Technology Process of N-Nitroso-2,6-dimethylmorpholine

There total 2 articles about N-Nitroso-2,6-dimethylmorpholine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

2,6-dimethyl morpholine (141-91-3) → N-nitroso-2,6-dimethylmorpholine (1456-28-6)

Guidance literature:

With Iron(III) nitrate nonahydrate; tetrabutylammonium perchlorate; In acetonitrile; at 70 ℃; Inert atmosphere; Electrolysis; Green chemistry;

DOI:10.1002/adsc.202000267

Reference yield:

→ N-nitroso-2,6-dimethylmorpholine (1456-28-6)

Guidance literature:

2,6-Dimethyl-morpholin, NaNO2, HCl;

upstream raw materials:

2,6-dimethyl morpholine

Refernces