1,8-dichloro-anthracene

Base Information

• Chemical Name: 1,8-dichloro-anthracene
• CAS No.: 14381-66-9
• Molecular Formula: C14H8Cl2
• Molecular Weight: 247.124
• Mol file: 14381-66-9.mol

Synonyms:1,8-Dichlor-anthracen;1,8-cichloro-anthracene;1,8-Dichloro-anthracene;1,8 dichloroanthracene;Anthracene, 1,8-dichloro-;

Chemical Property of 1,8-dichloro-anthracene

Chemical Property:

• Melting Point: 155 °C
• Boiling Point: 401.3±18.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.361±0.06 g/cm3(Predicted)
• LogP: 5.29980

Purity/Quality:

98% ^*data from raw suppliers

1,8-Dichloroanthracene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,8-dichloro-anthracene

There total 11 articles about 1,8-dichloro-anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4,5-dichloro-10H-anthracen-9-one (63605-29-8) → 1,8-dichloroanthracene (14381-66-9)

Guidance literature:

4,5-dichloro-10H-anthracen-9-one; With sodium tetrahydroborate; In isopropyl alcohol; for 2.5h; Inert atmosphere; Schlenk technique;

In methanol; isopropyl alcohol; Inert atmosphere; Schlenk technique;

With hydrogenchloride; In methanol; water; isopropyl alcohol; for 3h; pH=< 2; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.5b02737

Reference yield: 88.0%

1,8-dichloroanthraquinone (82-43-9) → 1,8-dichloroanthracene (14381-66-9)

Guidance literature:

With ammonium hydroxide; copper(II) sulfate; zinc; at 80 ℃; for 4.5h;

DOI:10.1021/ja00051a021

Reference yield: 18.0%

N-(4,5-Dichloro-anthracen-9-yl)-formamide (79917-75-2) → 1,8-dichloroanthracene (14381-66-9)

Guidance literature:

With formic acid; formamide; for 48h; Heating;

DOI:10.1021/jo00341a047

upstream raw materials:

1,8-dichloroanthraquinone

1,8-dichloro-9,10-dihydroanthracen-9-one

4,5-dichloro-10H-anthracen-9-one

1.8-Dichlor-9.10-dihydro-anthranol

Downstream raw materials:

1,8-di-o-tolylanthracene

anthracene-1,8-dicarboxylic acid

1,8-bis(phenylethynyl)anthracene

1,8-bis(4-methylphenyl)anthracene

Refernces

• 1、 Yang, Weiwei,Sinha Roy, Sayontani,Pitts, Winston C.,Nelson, Rebekah L.,Fronczek, Frank R.,Jurss, Jonah W.. "Electrocatalytic CO2 Reduction with Cis and Trans Conformers of a Rigid Dinuclear Rhenium Complex: Comparing the Monometallic and Cooperative Bimetallic Pathways". . p. 9564 - 9575. Retrieved 2018.
• 2、 Chmiel, Jasmin,Neumann, Beate,Stammler, Hans-Georg,Mitzel, Norbert W.. "Dialkylaluminium-, -gallium-, and -indium-based poly-lewis acids with a 1,8-diethynylanthracene backbone". . p. 11906 - 11914. Retrieved 2010.
• 3、 Manes, Taylor A.,Rose, Michael J.. "Mono- and Dinuclear Manganese Carbonyls Supported by 1,8-Disubstituted (L = Py, SMe, SH) Anthracene Ligand Scaffolds". . p. 5127 - 5138. Retrieved 2016.
• 4、 Manes, Taylor A.,Rose, Michael J.. "Redox properties of a bis-pyridine rhenium carbonyl derived from an anthracene scaffold". . p. 221 - 224. Retrieved 2015.
• 5、 -. "Organic light emitting element". Paragraph 0236-0240. . Retrieved 2021/01/24.