corallidictyal A

Base Information

• Chemical Name: corallidictyal A
• CAS No.: 160632-45-1
• Molecular Formula: C₂₂H₂₈O₄
• Molecular Weight: 356.462
• Mol file: 160632-45-1.mol

Synonyms:Spiro[benzofuran-2(6H),1'(2'H)-naphthalene]-7-carboxaldehyde,3',4',4'a,5',6',7',8',8'a-octahydro-5-hydroxy-2',5',5',8'a-tetramethyl-6-oxo-,(1'a,2'b,4'ab,8'aa)- (9CI); Corallidictyal A

Chemical Property of corallidictyal A

Chemical Property:

• Vapor Pressure: 7.52E-14mmHg at 25°C
• Boiling Point: 538.7°Cat760mmHg
• Flash Point: 187.3°C
• PSA: 63.60000
• Density: 1.21g/cm³
• LogP: 4.42190

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of corallidictyal A

There total 23 articles about corallidictyal A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

8-epi-siphonodictyal B → 8-epi-corallidictyal B (160632-45-1)

Guidance literature:

With silica gel; In ethyl acetate; at 20 ℃; for 20h;

Reference yield: 80.0%

(-)-corallidictyal D → (-)-corallidictyal B (160632-45-1)

Guidance literature:

With silver(l) oxide; In tetrahydrofuran; water; enantiospecific reaction; Inert atmosphere;

DOI:10.1039/c6ob02322c

Reference yield:

siphonodictyal B → corallidictyal A (160632-45-1) + corallidictyal B (160632-45-1)

Guidance literature:

With silica gel; In ethyl acetate; at 20 ℃; for 20h; Overall yield = 78percent; Overall yield = 10.1 mg;

upstream raw materials:

(+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

Refernces

• 1、 Dethe, Dattatraya H.,Dherange, Balu D.,Ali, Saghir,Parsutkar, Mahesh M.. "Enantiospecific total syntheses of meroterpenoids (-)-F1839-I and (-)-corallidictyals B and D". . p. 65 - 68. Retrieved 2016/12/27.