(+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

Base Information

Chemical Name:(+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol
CAS No.:124377-31-7
Molecular Formula:C₁₅H₂₆O
Molecular Weight:222.371
Hs Code.:

Synonyms:(+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

Suppliers and Price of (+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

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Technology Process of (+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

There total 1 articles about (+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 53163-41-0
((1S,2R,4aS,8aS)-2-hydroxy-2,5,5,8a-tetramethyldecahydronaphthalen-1-yl)methyl acetate

: 54632-04-1
albicanol

: 468-68-8
(-)-drimenol

: 124377-31-7
(+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

Guidance literature:: ((1S,2R,4aS,8aS)-2-hydroxy-2,5,5,8a-tetramethyldecahydronaphthalen-1-yl)methyl acetate; With pyridine; trichlorophosphate; at 20 ℃; for 2h;

With potassium hydroxide; In methanol; at 20 ℃; for 0.333333h; Title compound not separated from byproducts;
DOI:10.1007/s11172-005-0203-x

Reference yield: 83.0%

: 6100-60-3
4-methoxybenzene-1,3-diol

: 124377-31-7
(+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

: 4-methoxy-6-{[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methyl}benzene-1,3-diol

Guidance literature:: 4-methoxybenzene-1,3-diol; (+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol; In dichloromethane; at 20 ℃; for 0.0833333h; Inert atmosphere;

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;
DOI:10.1002/ejoc.201601503

Reference yield: 83.0%

: 6100-60-3
4-methoxybenzene-1,3-diol

: 124377-31-7
(+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol

: (4aS,6aR,12aR,12bS)-10-methoxy-4,4,6a,12b-tetramethyl-2,3,4,4a,5,6,6a,12,12a,12b-decahydro-1H-benzo[a]xanthen-9-ol

Guidance literature:: 4-methoxybenzene-1,3-diol; (+)-[(4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methanol; In dichloromethane; at 20 ℃; for 0.0833333h; Inert atmosphere;

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 6h; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.201601503