(E)-1-(Methoxymethoxy)-3,7-dimethylocta-2,6-diene

Base Information

• Chemical Name: (E)-1-(Methoxymethoxy)-3,7-dimethylocta-2,6-diene
• CAS No.: 70473-30-2
• Molecular Formula: C12H22O2
• Molecular Weight: 198.305
• European Community (EC) Number: 274-617-0
• DSSTox Substance ID: DTXSID501228113
• Nikkaji Number: J1.640.947B,J288.930G
• Mol file: 70473-30-2.mol

Synonyms:EINECS 274-617-0;(E)-1-(Methoxymethoxy)-3,7-dimethylocta-2,6-diene;70473-30-2;2,6-Octadiene, 1-(methoxymethoxy)-3,7-dimethyl-, (E)-;(2E)-1-(Methoxymethoxy)-3,7-dimethyl-2,6-octadiene;DTXSID501228113;1-(Methoxymethoxy)-3,7-dimethyl-2,6-octadiene

Chemical Property of (E)-1-(Methoxymethoxy)-3,7-dimethylocta-2,6-diene

Chemical Property:

• Vapor Pressure: 0.0272mmHg at 25°C
• Boiling Point: 254.7°Cat760mmHg
• Flash Point: 88.1°C
• PSA: 18.46000
• Density: 0.876g/cm³
• LogP: 3.29960
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 198.161979940
• Heavy Atom Count: 14
• Complexity: 189

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CCCC(=CCOCOC)C)C
• Isomeric SMILES: CC(=CCC/C(=C/COCOC)/C)C

Technology Process of (E)-1-(Methoxymethoxy)-3,7-dimethylocta-2,6-diene

There total 1 articles about (E)-1-(Methoxymethoxy)-3,7-dimethylocta-2,6-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Geraniol (106-24-1) + chloromethyl methyl ether (107-30-2) → (E)-1-(methoxymethoxy)-3,7-dimethylocta-2,6-diene (70473-30-2)

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2.5h; Inert atmosphere;

DOI:10.1039/d1ob00451d

Reference yield: 78.0%

(E)-1-(methoxymethoxy)-3,7-dimethylocta-2,6-diene (70473-30-2) + ethyl acetate (141-78-6) → 3,7-dimethyl-2E,6-octadien-1-yl acetate (105-87-3,8022-83-1)

Guidance literature:

With indium (III) iodide; for 15h; Heating;

DOI:10.1039/b104055n

Reference yield: 9.0%

(E)-1-(methoxymethoxy)-3,7-dimethylocta-2,6-diene (70473-30-2) + potassium (2-phenylethynyl)trifluoroborate → (E)-(3-((3,7-dimethylocta-2,6-dien-1-yl)oxy)prop-1-yn-1-yl)benzene (1327239-29-1)

Guidance literature:

potassium (2-phenylethynyl)trifluoroborate; With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

(E)-1-(methoxymethoxy)-3,7-dimethylocta-2,6-diene; In dichloromethane; at 23 ℃; regioselective reaction; Inert atmosphere;

DOI:10.1021/ja205174c

upstream raw materials:

Geraniol

chloromethyl methyl ether

Downstream raw materials:

((E)-1-isopropenyl-6-methoxymethoxy-4-methyl-hex-4-enylsulfanyl)-benzene

((E)-1-Isopropylidene-6-methoxymethoxy-4-methyl-hex-4-enylsulfanyl)-benzene

C₂₄H₃₀O₂S₂

3,7-dimethyl-2E,6-octadien-1-yl acetate