triphenylphosphane oxide - chloro(triphenyl)stannane (1:1)

Base Information

• Chemical Name: triphenylphosphane oxide - chloro(triphenyl)stannane (1:1)
• CAS No.: 6840-67-1
• Molecular Formula: C₃₆H₃₀ClOPSn
• Molecular Weight: 663.77
• Mol file: 6840-67-1.mol

Synonyms:

Chemical Property of triphenylphosphane oxide - chloro(triphenyl)stannane (1:1)

Chemical Property:

• Vapor Pressure: 2.62E-08mmHg at 25°C
• Boiling Point: 462.9°Cat760mmHg
• Flash Point: 233.8°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of triphenylphosphane oxide - chloro(triphenyl)stannane (1:1)

There total 3 articles about triphenylphosphane oxide - chloro(triphenyl)stannane (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

triphenyltin chloride (639-58-7) + Triphenylphosphine oxide (791-28-6) → (C6H5)3SnClOP(C6H5)3 (6840-67-1)

Guidance literature:

In chloroform; benzene; equimolar amt. of tin derivative and Ph3PO were refluxed in benzene/chloroform for about 1 h; petroleum ether (60-80°C) was added, if must, mixt. was kept in a fridge, solid was sepd., washed with petroleum ether, recrystd. from benzene/petroleum ether, dried in vac., elem. anal.;

Reference yield:

triphenyltin chloride (639-58-7) + Triphenylphosphine oxide (791-28-6) → chloro(triphenyl)(triphenylphoshineoxide)tin (6840-67-1)

Guidance literature:

In 1,2-dimethoxyethane; ca. 4 mM soln. of R3SnCl in soln. of 0.1 M TBAP in DME, room temp., under N2; detected and reaction monitored by polarography; Kinetics;

DOI:10.1016/S0022-328X(00)93815-4

Reference yield:

triphenyltin chloride (639-58-7) + triphenylphosphine (603-35-0) → chloro(triphenyl)(triphenylphoshineoxide)tin (6840-67-1)

Guidance literature:

In chloroform; dissolving equimolar amts. in CHCl3; slow evaporation of the solvent, crystn.;

upstream raw materials:

triphenyltin chloride

triphenylphosphine

Triphenylphosphine oxide

Downstream raw materials:

triphenyltin chloride*pyridine N-oxide