Silanol, dimethyl(1-methyl-1-phenylethyl)-

Base Information

• Chemical Name: Silanol, dimethyl(1-methyl-1-phenylethyl)-
• CAS No.: 144467-97-0
• Molecular Formula: C11H18OSi
• Molecular Weight: 194.349
• DSSTox Substance ID: DTXSID60438183
• Wikidata: Q82253830
• Mol file: 144467-97-0.mol

Synonyms:Silanol, dimethyl(1-methyl-1-phenylethyl)-;144467-97-0;SCHEMBL6404472;DTXSID60438183

Chemical Property of Silanol, dimethyl(1-methyl-1-phenylethyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 194.112691728
• Heavy Atom Count: 13
• Complexity: 169

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C1=CC=CC=C1)[Si](C)(C)O

Technology Process of Silanol, dimethyl(1-methyl-1-phenylethyl)-

There total 2 articles about Silanol, dimethyl(1-methyl-1-phenylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

chloro(α,α-dimethylbenzyl)dimethylsilane (118740-38-8) → (α,α-dimethylbenzyl)dimethylsilanol (144467-97-0)

Guidance literature:

With potassium hydroxide; In methanol; at 20 ℃; for 20h;

DOI:10.1016/S0040-4020(99)00649-3

Reference yield: 74.0%

phenyl(1-hydroxy-1-methylethyl)dimethylsilane (17993-95-2) → (α,α-dimethylbenzyl)dimethylsilanol (144467-97-0)

Guidance literature:

With ethylaluminum dichloride; In hexane; dichloromethane; for 1h; Ambient temperature;

DOI:10.1021/jo00050a034

Reference yield: 61.0%

(α,α-dimethylbenzyl)dimethylsilanol (144467-97-0) → (α,α-dimethyl-4-nitrobenzyl)dimethylsilanol (221325-34-4)

Guidance literature:

With ammonium nitrate; trifluoroacetic anhydride; In acetonitrile; at -15 - 20 ℃;

DOI:10.1016/S0040-4020(99)00649-3

upstream raw materials:

phenyl(1-hydroxy-1-methylethyl)dimethylsilane

chloro(α,α-dimethylbenzyl)dimethylsilane

Downstream raw materials:

(α,α-dimethyl-4-nitrobenzyl)dimethylsilanol

chloro(α,α-dimethyl-4-nitrobenzyl)dimethylsilane

N-(9-fluorenylmethoxycarbonyl)-O-[(4-amino-α,α-dimethylbenzyl)dimethylsilyl]-L-serine allyl ester

N-(9-fluorenylmethoxycarbonyl)-O-[(α,α-dimethyl-4-nitrobenzyl)dimethylsilyl]-L-serine allyl ester