1-Bromopyrene

Base Information

• Chemical Name: 1-Bromopyrene
• CAS No.: 1714-29-0
• Molecular Formula: C16H9Br
• Molecular Weight: 281.151
• Hs Code.: 29039990
• Mol file: 1714-29-0.mol

Synonyms:3-Bromopyrene;

Chemical Property of 1-Bromopyrene

Chemical Property:

• Appearance/Colour: light yellow solid
• Vapor Pressure: 5.91E-07mmHg at 25°C
• Melting Point: 102-105 °C
• Refractive Index: 1.858
• Boiling Point: 422.5 °C at 760 mmHg
• Flash Point: 209.4 °C
• PSA: 0.00000
• Density: 1.578 g/cm³
• LogP: 5.34650
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility.: Chloroform (Soluble), DMSO (Slightly, Heated, Sonicated), Methanol (Slightly)

Purity/Quality:

98.0%Min ^*data from raw suppliers

1-Bromopyrene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 1-Bromopyrene is used in the cleavage of DNA in studies. It is also used in the preparation of DNA base analogs. 1-Bromopyrene is suitable reagent used in the comparative study of effect of substituents of some pyrene derivatives in inducing phototoxicity, DNA damage and repair in human skin keratinocytes and light-induced lipid peroxidation in methanol. It is suitable reagent used in the study to investigate the UV photon-assisted thermal decomposition of PAHs at elevated temperature.1-Bromopyrene may be used as a standard to compare its spectral properties with that of pyrene based fluorescence probe. It may be used to study the effects of the addition of halogen hetero-atoms on the vapor pressures and thermodynamics of polycyclic aromatic hydrocarbons.It may be used in the synthesis of the following:2-methyl-4-pyren-1-yl-but-3-yn-2-ol1-ethynylpyrenesilsesquioxane (SSQ) based hybridruthenium nanoparticles functionalized with pyrene moietymono- and di-pyrenyl perfluoroalkanesoligo(1-bromopyrene)(OBrP) filmsdinitropyrene-derived DNA adduct

Technology Process of 1-Bromopyrene

There total 24 articles about 1-Bromopyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pyrene (129-00-0) → 1-bromopyrene (1714-29-0)

Guidance literature:

With N-Bromosuccinimide; In dichloromethane; for 2h;

Reference yield: 96.08%

C24H29BrO2 → 1-bromopyrene (1714-29-0)

Guidance literature:

With methanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 1h;

Reference yield: 93.24%

C24H29BrO2 → 1-bromopyrene (1714-29-0)

Guidance literature:

With methanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 1h; Inert atmosphere;

upstream raw materials:

tetrachloromethane

N-Bromosuccinimide

pyrene

benzene

Downstream raw materials:

1-pyrenyllithium

1,6-diphenylpyrene

1,3,6,8-tetraphenylpyrene

1-methoxypyrene

Refernces

• 1、 Chidirala, Swetha,Ulla, Hidayath,Valaboju, Anusha,Kiran, M. Raveendra,Mohanty, Maneesha Esther,Satyanarayan,Umesh,Bhanuprakash, Kotamarthi,Rao, Vaidya Jayathirtha. "Pyrene-Oxadiazoles for Organic Light-Emitting Diodes: Triplet to Singlet Energy Transfer and Role of Hole-Injection/Hole-Blocking Materials". . p. 603 - 614. Retrieved 2016.
• 2、 Yang,Finney. "A mechanistically-distinct approach to fluorescence visualization of singlet oxygen". . p. 11449 - 11452. Retrieved 2017.
• 3、 Guo, Yuxin,Wang, Lei,Zhuo, Jiezhen,Xu, Bo,Li, Xue,Zhang, Jianyu,Zhang, Zhiqiang,Chi, Haijun,Dong, Yan,Lu, Gonghao. "A pyrene-based dual chemosensor for colorimetric detection of Cu2+ and fluorescent detection of Fe3+". . p. 3951 - 3956. Retrieved 2017.
• 4、 Chowdhury, Jakir Ahmed,Moriguchi, Tomohisa,Shinozuka, Kazuo. "Pseudo-dumbbell-type molecular beacon probes bearing modified deoxyuridine derivatives and a silylated pyrene as a fluorophore". . p. 496 - 502. Retrieved 2015.
• 5、 Appalanaidu, E.,Baggi, T. R.,Harsha, K. G.,Rao, B. A.,Rao, V. J.. "ON–OFF Fluorescent Imidazole Derivative for Sensitive and Selective Detection of Copper(II) Ions". . p. 158 - 168. Retrieved 2020.
• 6、 Vattikunta, Radhika,Venkatakrishnarao, Dasari,Mohiddon, Mahamad Ahamad,Chandrasekar, Rajadurai. "Self-Assembly of “Chalcone” Type Push-Pull Dye Molecules into Organic Single Crystalline Microribbons and Rigid Microrods for Vis/NIR Range Photonic Cavity Applications". . p. 3435 - 3441. Retrieved 2016.
• 7、 -. "Method for preparing hydroxypyrene compound with high purity". Paragraph 0036-0038. . Retrieved 2021/03/16.
• 8、 -. "Thermally activated delayed fluorescent material and preparation method thereof". Paragraph 0017-0019. . Retrieved 2021/07/31.