Borane, tris(2,6-difluorophenyl)-

Base Information

Chemical Name:Borane, tris(2,6-difluorophenyl)-
CAS No.:146355-09-1
Molecular Formula:C18H9BF6
Molecular Weight:350.071
Hs Code.:
Mol file:146355-09-1.mol

Synonyms:

Suppliers and Price of Borane, tris(2,6-difluorophenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 5 raw suppliers

Chemical Property of Borane, tris(2,6-difluorophenyl)-

Chemical Property:

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Borane, tris(2,6-difluorophenyl)-

There total 4 articles about Borane, tris(2,6-difluorophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: C₁₈H₉BF₆*C₄H₈O

: 146355-09-1
tris(2,6-difluorophenyl)borane triethylphosphine oxide

Guidance literature:: With dimethylmonochlorosilane; at 20 ℃; for 3h; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1002/anie.201210175

Reference yield: 66.0%

: 64248-56-2
1-bromo-2,6-difluorobenzene

: 109-63-7
boron trifluoride diethyl etherate

: 146355-09-1
tris(2,6-difluorophenyl)borane triethylphosphine oxide

Guidance literature:: 1-bromo-2,6-difluorobenzene; With isopropylmagnesium chloride; In tetrahydrofuran; at -20 - 0 ℃; Inert atmosphere;

boron trifluoride diethyl etherate; In tetrahydrofuran; at -50 ℃; for 1h; Inert atmosphere;
DOI:10.1039/c9cc08749d

Reference yield: 46.0%

: 64248-56-2
1-bromo-2,6-difluorobenzene

: 353-42-4
boron trifluoride dimethyl etherate

: 146355-09-1
tris(2,6-difluorophenyl)borane triethylphosphine oxide

Guidance literature:: With magnesium; In tetrahydrofuran; toluene; addn. of 50mmol F2C6H3Br in 20ml THF to 50mmol Mg-filings in 50ml THF at -20°C; warming to room temp. after 4h; stirring for 14h; dropwise addn. of the mixture to 17mmol BCl3*OMe2 in 70ml toluene at -20°C; warming to room temp. after 4h;; removal of solvent; refluxing with n-hexane for 4h; removal of Mg-salts by filtration; crystn. from the filtrate; recrystn. from n-hexane; detn. by (13)C-, (19)F-, (1)H-NMR, m.p., mass spectroscopy;;