Gold(1+);triphenylphosphane;perchlorate

Base Information

Chemical Name:Gold(1+);triphenylphosphane;perchlorate
CAS No.:14853-97-5
Molecular Formula:C36H30AuP2.ClO4
Molecular Weight:820.999
Hs Code.:
DSSTox Substance ID:DTXSID50518362

Synonyms:14853-97-5;DTXSID50518362;Gold(1+) perchlorate--triphenylphosphane (1/1/2)

Suppliers and Price of Gold(1+);triphenylphosphane;perchlorate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Gold(1+);triphenylphosphane;perchlorate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:820.097356
Heavy Atom Count:44
Complexity:298

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[O-]Cl(=O)(=O)=O.[Au+]

Technology Process of Gold(1+);triphenylphosphane;perchlorate

There total 10 articles about Gold(1+);triphenylphosphane;perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: [(AuPPh3)3(μ-O)]ClO4

: 898801-09-7,899428-19-4
cis-[PtCl(acetimine)(PPh₃)2]ClO₄

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 14853-97-5
gold(I)-bis-triphenylphosphino-perchlorate

: cis-[PtCl(μ-N(AuPPh3)=CMe2)(PPh3)2]ClO4

Guidance literature:: In not given; at room temp.; not isolated, detected by NMR;
DOI:10.1021/ic060489i

Reference yield:

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: silver perchlorate

: 14853-97-5
gold(I)-bis-triphenylphosphino-perchlorate

Guidance literature:: With PPh₃; In tetrahydrofuran; methanol; byproducts: AgCl; AgClO4 in MeOH added to soln. of Au-complex in THF; AgCl filtered off; addn. of PPh3 in THF;; solvent removed; recrystn. (CH2Cl2/Et2O);;
DOI:10.1016/S0277-5387(00)80374-5

Reference yield:

: [(COD)Ph3PRh(μ-Im)AuPPh3]ClO4 COD=cyclooctadiene Im=imidazolate

: 14853-97-5
gold(I)-bis-triphenylphosphino-perchlorate

: [(CO)2Rh(μ-Im)]y Im=imidazolate

Guidance literature:: With CO; In dichloromethane; anhyd. CO bubbled for 20 min throuhg soln.; recrystd. from chloroform/ether; filtrate evapd. to dryness, ((CO)2Rh(μ-Im))y pptd. with methanol/water (1/2);
DOI:10.1016/S0022-328X(00)89059-2