Silver, (pentafluorophenyl)-

Base Information

• Chemical Name: Silver, (pentafluorophenyl)-
• CAS No.: 30123-12-7
• Molecular Formula: C6AgF5
• Molecular Weight: 274.926
• Mol file: 30123-12-7.mol

Synonyms:

Chemical Property of Silver, (pentafluorophenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silver, (pentafluorophenyl)-

There total 15 articles about Silver, (pentafluorophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trimethyl(pentafluorophenyl)silane (1206-46-8) + silver fluoride (11113-87-4) → silver(I)pentafluorobenzene (30123-12-7)

Guidance literature:

at 20 ℃; for 2h;

DOI:10.1002/anie.201801452

Reference yield: 90.0%

silver fluoride (11113-87-4) + lithium tetrakis(pentafluorophenyl)borate (2797-28-6) → silver(I)pentafluorobenzene (30123-12-7)

Guidance literature:

In dichloromethane; at 40 - 60 ℃; for 8h; Sonication; Inert atmosphere;

DOI:10.1021/acs.organomet.5b00492

Reference yield: 85.0%

NBu4[Ag(C6F5)2] + silver perchlorate → pentafluorophenyl silver(I) (30123-12-7)

Guidance literature:

In diethyl ether; byproducts: [Bu4N]ClO4; mixt. of educts in Et2O stirred for 45 min under N2 at room temp.; filtered, evapd., solid washed with hexane;

DOI:10.1016/S0022-328X(00)98739-4

upstream raw materials:

perfluoropropylene

bromopentafluorobenzene

silver fluoride

water

Downstream raw materials:

bromopentafluorobenzene

2,3,4,5,6-pentafluorotoluene

pentafluorophenyl copper

2',3',4',5',6'-pentafluoroacetophenone

Refernces

• 1、 Ibad, Muhammad Farooq,Schulz, Axel,Villinger, Alexander. "Pentafluorophenyl Silver: Structure and Bonding of Arene Solvates". . p. 3893 - 3901. Retrieved 2015.
• 2、 Li, Weipeng,Yuan, Dandan,Wang, Guoqiang,Zhao, Yue,Xie, Jin,Li, Shuhua,Zhu, Chengjian. "Cooperative Au/Ag Dual-Catalyzed Cross-Dehydrogenative Biaryl Coupling: Reaction Development and Mechanistic Insight". supporting information. p. 3187 - 3197. Retrieved 2019/02/19.