Platinum--triphenylphosphane (1/2)

Base Information

• Chemical Name: Platinum--triphenylphosphane (1/2)
• CAS No.: 15094-61-8
• Molecular Formula: C36H30P2Pt
• Molecular Weight: 719.662
• DSSTox Substance ID: DTXSID60530696
• Mol file: 15094-61-8.mol

Synonyms:Platinum--triphenylphosphane (1/2);15094-61-8;SCHEMBL5085342;DTXSID60530696

Chemical Property of Platinum--triphenylphosphane (1/2)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 719.147069
• Heavy Atom Count: 39
• Complexity: 202

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pt]

Technology Process of Platinum--triphenylphosphane (1/2)

There total 8 articles about Platinum--triphenylphosphane (1/2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + Cp*2Rh2(CO)2 → Rh2(CO)3(C5(CH3)5)2PtP(C6H5)3 + tris(triphenylphosphine)platinum(0) (13517-35-6) + bis(triphenylphosphine)platinum(0) (15094-61-8) + Pt(P(C6H5)3) (47028-70-6)

Guidance literature:

In diethyl ether; under N2, mixt. of Rh- and Pt-complexes (molar ratio 1:1) in Et2O stirred for 16 h at room temp.; solvent removed, extd. with light petroleum, extracts reduced, chromd. (alumina column, light petroleum-Et2O);

Reference yield:

dioxygenbis(triphenylphosphine)platinum(0) (29894-57-3) → bis(triphenylphosphine)platinum(0) (15094-61-8) + oxygen (80937-33-3)

Guidance literature:

In chloroform; Irradiation (UV/VIS); in a deaerated soln. of CHCl3; singlet O2 was scavenged by 2,2,6,6-tetramethylpiperidine and detected by ESR, or by 1,3-diphenylisobenzofurane and detected by UV;

DOI:10.1021/ja00410a045

Reference yield:

bis(triphenylphosphine)platinum(η2-C60) (135863-99-9) → bis(triphenylphosphine)platinum(0) (15094-61-8) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0)

Guidance literature:

In tetrahydrofuran; react. at 25, 19, 14, 9, 4, -14, -19 and -23°C; rate consts. given; Kinetics;

DOI:10.1021/ja00046a029

upstream raw materials:

cis-[bis(triphenylphosphane)diazidoplatinum(II)]

tris(triphenylphosphine)platinum⁽⁰⁾

Pt(N₃)2(P(C₆H₅)3)2

dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

Downstream raw materials:

PtH(P(C₆H₅)3)2(SH)

tris(triphenylphosphine)platinum⁽⁰⁾