29894-57-3

Basic information

• Product Name: dioxygenbis(triphenylphosphine)platinum⁽⁰⁾
• Synonyms: dioxygenbis(triphenylphosphine)platinum⁽⁰⁾
• CAS NO: 29894-57-3
• Molecular Weight: 751.661
• Mol File: 29894-57-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: dioxygenbis(triphenylphosphine)platinum⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: dioxygenbis(triphenylphosphine)platinum⁽⁰⁾(29894-57-3)
• EPA Substance Registry System: dioxygenbis(triphenylphosphine)platinum⁽⁰⁾(29894-57-3)

Safety Data

• Hazardous Substances Data: 29894-57-3(Hazardous Substances Data)

Upstream product

• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 137507-02-9 tetrakis{tri(2-pyridyl)phosphine}platinum⁽⁰⁾ 
• 102982-51-4 Pt(P(C₆H₅)3)2(OOH)(HCONC₆H₅) 

Downstream Products

• 29933-56-0 ((C₆H₅)3P)2PtOC₆H₁₀OO 
• 102982-53-6 (hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II) 
• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 17030-86-3 bis(triphenylphosphine)carbonateplatinum(II) 
• 791-28-6 Triphenylphosphine oxide 
• 15094-61-8 bis(triphenylphosphine)platinum⁽⁰⁾ 
• 80937-33-3 oxygen 
• 102982-54-7 Pt((C₆H₅)3P)2(OOH)(C₆H₅O) 
• 22455-21-6 Pt((C₆H₅)3P)2(OC(CH₃)2OO) 
• 69503-11-3 Pt(P(C₆H₅)3)2(O₂C(CH₂CO₂CH₃)2O) 
• 56213-50-4 [Pt(SCH₃)2(P(C₆H₅)3)2] 
• 102982-55-8 Pt(P(C₆H₅)3)2(NC(O)CH₂CH₂CO)2 
• 76583-22-7 cis-bis(thiolo)bis(triphenylphosphine)platinum(II) 
• 76583-25-0 cis-Pt(SBu)2(PPh₃)2 

Relevant articles and documents

Synthesis and chemistry of 2-pyridyl(phosphine) complexes of platinum(0)

The complexes tetrakisplatinum(0), 1, and trisplatinum(0), 2, are synthesized, and characterized by 31P and 195Pt NMR spectroscopy.The reactions of 1 and 2 with olefins (ethylene, maleic anhydride, diethyl maleate, and olefinic nitriles) are studied and some square-planar Pt(PR3)2(η2-olefin) species isolated (PR3 = the pyridylphosphine).No olefin hydration products are observed on heating the olefin complexes in aqueous solution.Oxidative addition of MeI to 1 and 2 gives the trans-PtI(Me)(PR3)2 species.However, the trans-Pt(H)Cl(PR3)2 species is isolated only from reaction of 2 with gaseous HCl; the hydride reacts with acrylonitrile to form cis-PtCl(CH2CH2CN)(PR3)2.

REACTIONS OF AMINES AND RELATED SPECIES WITH TRANSITION METAL PEROXO COMPLEXES

The reactions of amines and related species with molecular oxygen bound to a transition metal centre, are reviewed briefly.New results on the reactions of Pt(PPh3)2O2 with amine derivatives such as formanilides and imides are reported; from these reactions new amidohydroperoxoplatinum(II) complexes have been isolated.The related reaction of Pt(PPh3)2O2 with phenol is also described.A general mechanism for these deprotonation reactions is discussed.