(E)-Cycloundecene

Base Information

• Chemical Name: (E)-Cycloundecene
• CAS No.: 13151-60-5
• Molecular Formula: C11H20
• Molecular Weight: 152.28
• Hs Code.: 2902199090
• Nikkaji Number: J401.908C
• Mol file: 13151-60-5.mol

Synonyms:(E)-Cycloundecene;Cycloundecene(E);13151-60-5;t-Cycloundecene;trans-Cycloundecene;GMUVJAZTJOCSND-OWOJBTEDSA-N

Chemical Property of (E)-Cycloundecene

Chemical Property:

• Vapor Pressure: 0.207mmHg at 25°C
• Boiling Point: 216.3°C at 760 mmHg
• Flash Point: 76.1°C
• PSA: 0.00000
• Density: 0.808g/cm³
• LogP: 4.06710
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 152.156500638
• Heavy Atom Count: 11
• Complexity: 90.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCCC=CCCCC1
• Isomeric SMILES: C1CCCC/C=C/CCCC1

Technology Process of (E)-Cycloundecene

There total 10 articles about (E)-Cycloundecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

12,12-dimorpholino-trans-bicyclo<9.1.0>dodecane (79985-05-0,80009-84-3) → trans-cycloundecane (13151-60-5) + 5-morpholino-2,3,6,7-tetrahydro-1,4-oxazepine (113628-18-5)

Guidance literature:

at 650 ℃; under 1E-05 - 0.0001 Torr;

DOI:10.1021/jo00243a040

Reference yield:

Cycloundecyl-phenylacetat (42463-70-7) → trans-cycloundecane (13151-60-5)

Guidance literature:

With (photolysis); In hexane; Quantum yield; Irradiation;

DOI:10.1021/ja00797a022

Reference yield:

cycloundecanone (878-13-7) → trans-cycloundecane (13151-60-5)

Guidance literature:

Multi-step reaction with 3 steps

1: Raney nickel; methanol / 100 °C / 58840.6 Torr / Hydrogenation

With methanol; nickel;

DOI:10.1002/hlca.19550380714

upstream raw materials:

cycloundecanol

cis-Cycloundecen

toluene-4-sulfonic acid

acetic acid

Downstream raw materials:

cis-Cycloundecen

cycloundecanone

Refernces

• 1、 Cope et al.. "-". . p. 3153. Retrieved 1959.
• 2、 Aubert, Corinne,Begue, Jean-Pierre,Biellmann, Jean-Francois. "β'β ANIONIC ELIMINATION OF CARBOXYLIC ESTERS". . p. 5581 - 5590. Retrieved 2007/10/02.