2(3H)-Furanone, 5-(3-hexenyl)dihydro-, (R-(Z))-

Base Information

• Chemical Name: 2(3H)-Furanone, 5-(3-hexenyl)dihydro-, (R-(Z))-
• CAS No.: 155682-86-3
• Molecular Formula: C10H16O2
• UNII: X12NB2ST6R
• Nikkaji Number: J1.459.233D
• Wikidata: Q27293255
• Mol file: 155682-86-3.mol

Synonyms:UNII-X12NB2ST6R;X12NB2ST6R;(R)-(+-)-gamma-Jasmolactone;2(3H)-Furanone, 5-(3-hexenyl)dihydro-, (R-(Z))-;155682-86-3;7-Decen-4-olide, (Z)-(+-)-;2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-, (5R)-;FEMA No. 4439, Z-(+-)-;2(3H)-Furanone, 5-(3Z)-3-hexen-1-yldihydro-, (5R)-;(Z)-(+)-7-decen-4-olide;(R)-(+)-.GAMMA.-JASMOLACTONE;7-DECEN-4-OLIDE, (Z)-(+)-;FEMA NO. 4439, Z-(+)-;Q27293255

Chemical Property of 2(3H)-Furanone, 5-(3-hexenyl)dihydro-, (R-(Z))-

Chemical Property:

• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 168.115029749
• Heavy Atom Count: 12
• Complexity: 173

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCC=CCCC1CCC(=O)O1
• Isomeric SMILES: CC/C=C\CC[C@@H]1CCC(=O)O1

Technology Process of 2(3H)-Furanone, 5-(3-hexenyl)dihydro-, (R-(Z))-

There total 10 articles about 2(3H)-Furanone, 5-(3-hexenyl)dihydro-, (R-(Z))- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C19H27NO3 (1233882-55-7) → (R)-(+)-γ-jasmolactone (155682-86-3,67114-38-9,93787-95-2,97416-87-0)

Guidance literature:

C₁₉H₂₇NO₃; With methanol; sodium hydroxide; for 3h; Reflux;

With hydrogenchloride; In water; at 20 ℃; for 1h;

DOI:10.1080/00397910903134618

Reference yield: 55.0%

n-propyltriphenylphosphonium bromide (6228-47-3) + 3-(5-oxotetrahydro-2-furanyl)propanal (127299-66-5) → (R)-(+)-γ-jasmolactone (155682-86-3,67114-38-9,93787-95-2,97416-87-0) + (S)-(-)-γ-jasmolactone (67114-38-9,93787-95-2,97416-87-0)

Guidance literature:

n-propyltriphenylphosphonium bromide; With lithium hexamethyldisilazane; In tetrahydrofuran; at 0 ℃; for 0.166667h;

3-(5-oxotetrahydro-2-furanyl)propanal; In tetrahydrofuran;

DOI:10.1016/S0957-4166(00)00444-4

Reference yield:

C24H28N2O5 (1233882-70-6) → (R)-(+)-γ-jasmolactone (155682-86-3,67114-38-9,93787-95-2,97416-87-0)

Guidance literature:

C₂₄H₂₈N₂O₅; With methanol; sodium hydroxide; for 3h; Reflux;

With hydrogenchloride; In water; at 20 ℃; for 1h;

DOI:10.1080/00397910903134618

upstream raw materials:

n-propyltriphenylphosphonium bromide

3-(5-oxotetrahydro-2-furanyl)propanal

R-(+) estere benzilico dell'acido γ-butirrolatton-γ-3-propionico

γ-(Z)-dec-7-enlactone