Gold, bromobis(triphenylphosphine)-

Base Information

• Chemical Name: Gold, bromobis(triphenylphosphine)-
• CAS No.: 15656-52-7
• Molecular Formula: C₃₆H₃₀AuBrP₂
• Molecular Weight: 801.452
• Mol file: 15656-52-7.mol

Synonyms:

Chemical Property of Gold, bromobis(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Gold, bromobis(triphenylphosphine)-

There total 1 articles about Gold, bromobis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + (naphthalene-1,8-diyl)dilithium (61767-59-7) + triphenylantimony dibromide (20265-30-9) + triphenylphosphine (603-35-0) → (triphenylphosphine)2AuBr (15656-52-7,15810-46-5) + Au(1,8-naphthalenediyl)2SbPh2

Guidance literature:

In tetrahydrofuran; (N2); addn. of THF soln. of antimony compd. to THF soln. of dilithionaphthalene at room temp., stirring for 10 min, addn. of THF soln. of gold compd. and phosphine deriv.; layering with diethyl ether and hexane, keeping for 2 ds at room temp., isolation of crystals, multiple recrystn. (hot CH2Cl2), elem. anal.;

DOI:10.1021/ja201092g

upstream raw materials:

(tetrahydrothiophene)gold(I) chloride

(naphthalene-1,8-diyl)dilithium

triphenylantimony dibromide

triphenylphosphine