1-{[tert-Butyl(diphenyl)silyl]oxy}pent-4-en-2-ol

Base Information

Chemical Name:1-{[tert-Butyl(diphenyl)silyl]oxy}pent-4-en-2-ol
CAS No.:157920-00-8
Molecular Formula:C21H28O2Si
Molecular Weight:340.538
Hs Code.:
DSSTox Substance ID:DTXSID00563685
Nikkaji Number:J1.879.099H
Mol file:157920-00-8.mol

Synonyms:157920-00-8;1-{[tert-Butyl(diphenyl)silyl]oxy}pent-4-en-2-ol;DTXSID00563685

Suppliers and Price of 1-{[tert-Butyl(diphenyl)silyl]oxy}pent-4-en-2-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 1-{[tert-Butyl(diphenyl)silyl]oxy}pent-4-en-2-ol

Chemical Property:

Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:8
Exact Mass:340.185856666
Heavy Atom Count:24
Complexity:358

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OCC(CC=C)O

Technology Process of 1-{[tert-Butyl(diphenyl)silyl]oxy}pent-4-en-2-ol

There total 9 articles about 1-{[tert-Butyl(diphenyl)silyl]oxy}pent-4-en-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 103625-11-2
(±)-pent-4-en-1,2-diol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 157920-00-8
1-(tert-butyldiphenylsilanyloxy)pent-4-en-2-ol

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 - 20 ℃; for 5h;
DOI:10.1016/S0040-4020(01)85238-8

Reference yield: 87.0%

: C₁₉H₂₂O₃Si

: 106-95-6
allyl bromide

: 157920-00-8
1-(tert-butyldiphenylsilanyloxy)pent-4-en-2-ol

Guidance literature:: With tin; In ethanol; water; at 25 ℃; for 12h; Inert atmosphere;
DOI:10.1002/chem.201601471

Reference yield:

: 115869-43-7
(tert-butyldiphenylsilanyloxy)acetaldehyde

: 72824-04-5
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 157920-00-8
1-(tert-butyldiphenylsilanyloxy)pent-4-en-2-ol

Guidance literature:: (tert-butyldiphenylsilanyloxy)acetaldehyde; 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; With scandium tris(trifluoromethanesulfonate); In dichloromethane; at -78 ℃; for 16h;

With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 0.5h;
DOI:10.1021/ja036807j