Carbamodithioic acid, (4-bromophenyl)-, monoammonium salt

Base Information

• Chemical Name: Carbamodithioic acid, (4-bromophenyl)-, monoammonium salt
• CAS No.: 15866-99-6
• Molecular Formula: C7H6BrNS2.H3N
• Molecular Weight: 265.198
• Mol file: 15866-99-6.mol

Synonyms:

Chemical Property of Carbamodithioic acid, (4-bromophenyl)-, monoammonium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbamodithioic acid, (4-bromophenyl)-, monoammonium salt

There total 1 articles about Carbamodithioic acid, (4-bromophenyl)-, monoammonium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + 4-bromo-aniline (106-40-1) → ammonium 4-bromophenyldithiocarbamate (15866-99-6)

Guidance literature:

With ammonium hydroxide; In methanol; for 1.33333h; Cooling with ice;

DOI:10.14233/ajchem.2017.20481

Reference yield: 77.0%

ammonium 4-bromophenyldithiocarbamate (15866-99-6) + 4-chloroacetylhydrazino-2-phenyl-phthalazin-1(2H)-one (161238-54-6) → (4-bromo-phenyl)-dithiocarbamic acid N'-(4-oxo-3-phenyl-3,4-dihydro-phthalazin-1-yl)-hydrazinocarbonylmethyl ester

Guidance literature:

In pyridine; acetone; at 20 ℃; for 7h; Heating;

Reference yield: 39.0%

ammonium 4-bromophenyldithiocarbamate (15866-99-6) → 4-Bromophenyl isothiocyanate (1985-12-2)

Guidance literature:

With lead(II) nitrate; In water; at 10 - 20 ℃; for 1h;

DOI:10.1016/j.inoche.2021.108509

upstream raw materials:

carbon disulfide

4-bromo-aniline

Downstream raw materials:

3-(4-bromo-phenyl)-4-phenethyl-3H-thiazole-2-thione

3-(4-bromo-phenyl)-4,5,6,7-tetrahydro-3H-benzothiazole-2-thione

3-(4-bromophenyl)-4-methyl-5-ethoxycarbonyl-3H-thiazole-2-thione

3-(4-bromo-phenyl)-4-(4-chloro-phenyl)-3H-thiazole-2-thione