Silane, [[6-[[2-chloro-5-(trifluoromethyl)phenoxy]methyl]-1,2-dithiin-3-yl]methoxy] (1,1-dimethylethyl)dimethyl-

Base Information

Chemical Name:Silane, [[6-[[2-chloro-5-(trifluoromethyl)phenoxy]methyl]-1,2-dithiin-3-yl]methoxy] (1,1-dimethylethyl)dimethyl-
CAS No.:165404-94-4
Molecular Formula:C19H24ClF3O2S2Si
Molecular Weight:469.064
Hs Code.:
Mol file:165404-94-4.mol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, [[6-[[2-chloro-5-(trifluoromethyl)phenoxy]methyl]-1,2-dithiin-3-yl]methoxy] (1,1-dimethylethyl)dimethyl-

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Technology Process of Silane, [[6-[[2-chloro-5-(trifluoromethyl)phenoxy]methyl]-1,2-dithiin-3-yl]methoxy] (1,1-dimethylethyl)dimethyl-

There total 5 articles about Silane, [[6-[[2-chloro-5-(trifluoromethyl)phenoxy]methyl]-1,2-dithiin-3-yl]methoxy] (1,1-dimethylethyl)dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 40889-91-6
2-chloro-5-(trifluoromethyl)phenol

: 165404-83-1
3-[(tert-butyldimethylsilyloxy)methyl]-6-(hydroxymethyl)-1,2-dithiin

: 165404-94-4
3-[(tert-butyldimethylsilyloxy)methyl]-6-[(2-chloro-5-trifluoromethyl-phenyloxy)methyl]-1,2-dithiin

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 0 - 20 ℃; for 17.5h;
DOI:10.1021/jm00014a016

Reference yield:

: ethyl acetate n-hexane

: 40889-91-6
2-chloro-5-(trifluoromethyl)phenol

: 165404-83-1
3-[(tert-butyldimethylsilyloxy)methyl]-6-(hydroxymethyl)-1,2-dithiin

: 1972-28-7,218603-74-8
diethylazodicarboxylate

: 165404-94-4
3-[(tert-butyldimethylsilyloxy)methyl]-6-[(2-chloro-5-trifluoromethyl-phenyloxy)methyl]-1,2-dithiin

Guidance literature:: With triphenylphosphine; In tetrahydrofuran;

Reference yield:

: 2,5-bis<(2-cyanoethyl)thio>-2,4-hexadiene-1,6-diol

: 165404-94-4
3-[(tert-butyldimethylsilyloxy)methyl]-6-[(2-chloro-5-trifluoromethyl-phenyloxy)methyl]-1,2-dithiin

Guidance literature:: Multi-step reaction with 3 steps

1: 49.3 percent / imidazole / dimethylformamide / 16 h / Ambient temperature

2: 1.) t-BuOK, 2.) aq. K₃FeCN₆ / 1.) eter, 11 min, 2.) eter, 12 min

3: 62 percent / triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 17.5 h / 0 - 20 °C

With 1H-imidazole; potassium tert-butylate; triphenylphosphine; potassium hexacyanoferrate(III); diethylazodicarboxylate; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jm00014a016