4-Penten-2-ol, 1-(triphenylmethoxy)-, (2S)-

Base Information

Chemical Name:4-Penten-2-ol, 1-(triphenylmethoxy)-, (2S)-
CAS No.:170277-82-4
Molecular Formula:C24H24O2
Molecular Weight:344.453
Hs Code.:
DSSTox Substance ID:DTXSID50444879
Nikkaji Number:J1.224.319G
Mol file:170277-82-4.mol

Synonyms:4-Penten-2-ol, 1-(triphenylmethoxy)-, (2S)-;170277-82-4;SCHEMBL8502919;DTXSID50444879;KDYRNYXQEPYCTD-QHCPKHFHSA-N;(S)-1-(Trityloxy)-4-pentene-2-ol;(S)-1-(triphenylmethoxy)-4-penten-2-ol

Suppliers and Price of 4-Penten-2-ol, 1-(triphenylmethoxy)-, (2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 4-Penten-2-ol, 1-(triphenylmethoxy)-, (2S)-

Chemical Property:

XLogP3:5.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:8
Exact Mass:344.177630004
Heavy Atom Count:26
Complexity:355

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CCC(COC(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)O
Isomeric SMILES:C=CC[C@@H](COC(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)O

Technology Process of 4-Penten-2-ol, 1-(triphenylmethoxy)-, (2S)-

There total 13 articles about 4-Penten-2-ol, 1-(triphenylmethoxy)-, (2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1826-67-1
vinyl magnesium bromide

: 129940-50-7
(S)-tritylglycidol

: 170277-82-4
(2S)-1-triphenylmethoxy-4-pentene-2-ol

Guidance literature:: With copper(l) iodide; In tetrahydrofuran; at -40 - -10 ℃; Inert atmosphere;
DOI:10.1021/acschemneuro.8b00196

Reference yield: 91.0%

: 3292-82-8
α-trityloxyacetaldehyde

: 170277-82-4
(2S)-1-triphenylmethoxy-4-pentene-2-ol

Guidance literature:: α-trityloxyacetaldehyde; cyclopentadienyl[(4R,trans)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato-O,O']-2-propenyltitanium; In diethyl ether; at -78 ℃; for 4h;

With water; for 12h;
DOI:10.1016/S0957-4166(99)00390-0

Reference yield: 75.0%

: 129940-50-7
(S)-tritylglycidol

: 85550-19-2
(S)-1-triphenylmethoxypropan-2-ol

: 170277-82-4
(2S)-1-triphenylmethoxy-4-pentene-2-ol

: (R)-1-Bromo-3-trityloxy-propan-2-ol

Guidance literature:: With vinyl magnesium bromide; In tetrahydrofuran; at -30 ℃; other reagent: CuI/vinylmagnesium bromide;
DOI:10.1021/jo971980h