Acetamide, 2-(hydroxyimino)-N-(4-methoxy-2-nitrophenyl)-

Base Information

Chemical Name:Acetamide, 2-(hydroxyimino)-N-(4-methoxy-2-nitrophenyl)-
CAS No.:172162-01-5
Molecular Formula:C9H9N3O5
Molecular Weight:239.188
Hs Code.:

Synonyms:

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Chemical Property of Acetamide, 2-(hydroxyimino)-N-(4-methoxy-2-nitrophenyl)-

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Technology Process of Acetamide, 2-(hydroxyimino)-N-(4-methoxy-2-nitrophenyl)-

There total 1 articles about Acetamide, 2-(hydroxyimino)-N-(4-methoxy-2-nitrophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 302-17-0
chloral hydrate

: 96-96-8
4-methoxy-2-nitroaniline

: 172162-01-5
N-(4-methoxy-2-nitrophenyl)-2-(N-hydroxyimino)acetamide

Guidance literature:: With hydroxylamine hydrochloride; sodium sulfate; In water; at 55 ℃;
DOI:10.1080/10587259508038696

Reference yield:

: 172162-01-5
N-(4-methoxy-2-nitrophenyl)-2-(N-hydroxyimino)acetamide

: (+/-)-2,2'-dimethyl-6,6'-dinitro-4,4'-bis<(4-n-octyloxybenzoyl)oxy>biphenyl

Guidance literature:: Multi-step reaction with 10 steps

1: 83 percent / conc. H₂SO₄ / 0.25 h / 95 °C

2: 30percent aq. H₂O₂, 2M aq. NaOH / Ambient temperature

3: 1.) conc. H₂SO₄, NaNO₂, 85percent aq. H₃PO₄, 2.) aq. KI / 1.) 5 deg C, 1 h, 2.) RT, overnight

4: conc. H₂SO₄ / 12 h / Heating

5: 72 percent / Cu bronze / dimethylformamide / Heating

6: 98 percent / aq. NaOH / ethanol / Heating

7: BH₃*THF / tetrahydrofuran / 20 h / Ambient temperature

8: 48percent aq. HBr, glacial AcOH / 24 h / Heating

9: 76 percent / NaBH₃CN, HMPA / 20 h / 55 °C

10: 89 percent / DCC, DMAP / CH₂Cl₂ / 24 h / Ambient temperature

With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium hydroxide; borane-THF; copper bronze; phosphoric acid; sulfuric acid; hydrogen bromide; dihydrogen peroxide; sodium cyanoborohydride; acetic acid; dicyclohexyl-carbodiimide; potassium iodide; sodium nitrite; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja9617505

Reference yield:

: 172162-01-5
N-(4-methoxy-2-nitrophenyl)-2-(N-hydroxyimino)acetamide

: 172162-03-7
2-iodo-5-methoxy-3-nitrobenzoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / conc. H₂SO₄ / 0.25 h / 95 °C

2: 30percent aq. H₂O₂, 2M aq. NaOH / Ambient temperature

3: 1.) conc. H₂SO₄, NaNO₂, 85percent aq. H₃PO₄, 2.) aq. KI / 1.) 5 deg C, 1 h, 2.) RT, overnight

With sodium hydroxide; phosphoric acid; sulfuric acid; dihydrogen peroxide; potassium iodide; sodium nitrite;
DOI:10.1021/ja9617505