Bifenox

Base Information

• Chemical Name: Bifenox
• CAS No.: 42576-02-3
• Deprecated CAS: 12680-11-4,51142-56-4
• Molecular Formula: C14H9Cl2NO5
• Molecular Weight: 342.135
• Hs Code.: 2918990090
• European Community (EC) Number: 255-894-7,642-906-4
• UNII: KSB85XT26Y
• DSSTox Substance ID: DTXSID1040320
• Nikkaji Number: J3.509B
• Wikipedia: Bifenox
• Wikidata: Q424830
• Metabolomics Workbench ID: 67729
• ChEMBL ID: CHEMBL449928
• Mol file: 42576-02-3.mol

Synonyms:2,4-dichlorophenyl-3'-carboxymethyl-4'-nitrophenyl ether;bifenox

Chemical Property of Bifenox

Chemical Property:

• Melting Point: 83 - 85oC
• Refractive Index: 1.7350 (estimate)
• Boiling Point: 420.958 °C at 760 mmHg
• Flash Point: 208.388 °C
• PSA: 81.35000
• Density: 1.464 g/cm³
• LogP: 5.00370
• Storage Temp.: 0-6°C
• Water Solubility.: 0.5mg/L(temperature not stated)
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 340.9857778
• Heavy Atom Count: 22
• Complexity: 417

Purity/Quality:

97% ^*data from raw suppliers

Bifenox ^*data from reagent suppliers

Safty Information:

• Pictogram(s): N
• Hazard Codes: N
• Statements: 50/53
• Safety Statements: 60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Herbicides, Protox-Inhibiting
• Canonical SMILES: COC(=O)C1=C(C=CC(=C1)OC2=C(C=C(C=C2)Cl)Cl)[N+](=O)[O-]
• Uses: Herbicide. Selective preemergence or postemergence herbicide used to effectively control a wide variety of broad-leaved weeds (such as bindweed, jimsonweed, kochia, mustards, pigweeds, sesbania, smartweed and velvet-leaf) in tolerant crops (corn, grain sorghum, maize, rice and soybeans).

Technology Process of Bifenox

There total 1 articles about Bifenox which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ bifenox (42576-02-3)

Guidance literature:

entspr.Isopropylester, MeOH, NaOMe;

Reference yield:

bifenox (42576-02-3) → nitrofen (1836-75-5) + 2,4-dichlorophenol (120-83-2,40477-79-0)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); cyclomaltooctaose; In dimethyl sulfoxide; Electrochemical reaction;

DOI:10.1135/cccc2009509

Reference yield:

bifenox (42576-02-3) → 5-(2,4-dichlorophenoxy)-2-aminobenzoate + nitrofen (1836-75-5) + 2,4-dichlorophenol (120-83-2,40477-79-0)

Guidance literature:

With β‐cyclodextrin; In dimethyl sulfoxide; Electrochemical reaction;

DOI:10.1135/cccc2009509

Downstream raw materials:

2-nitro-5-(2',4'-dichlorophenoxy)benzoic acid

methyl 5-(2,4-dichlorophenoxy)-2-nitrosobenzoate

2,4-dichlorophenol

nitrofen