5-METHYLFURFURYLACETATE

Base Information

• Chemical Name: 5-METHYLFURFURYLACETATE
• CAS No.: 18091-24-2
• Molecular Formula: C8H10O3
• Molecular Weight: 154.166
• Mol file: 18091-24-2.mol

Synonyms:Essigsaeure-(5-methyl-furfurylester);acetic acid-(5-methyl-furfuryl ester);

Chemical Property of 5-METHYLFURFURYLACETATE

Chemical Property:

• PSA: 39.44000
• LogP: 1.65110

Purity/Quality:

99.90% ^*data from raw suppliers

(5-methylfuran-2-yl)methylacetate 97.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-METHYLFURFURYLACETATE

There total 11 articles about 5-METHYLFURFURYLACETATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.1%

fructose (57-48-7,87-79-6,87-81-0,551-68-8,3615-39-2,3615-56-3,6035-50-3,7776-48-9,16354-64-6,17598-81-1,17598-82-2,23140-52-5,30237-26-4,65732-90-3,73952-10-0,73952-11-1,139686-85-4,18875-34-8) + acetic acid (64-19-7,77671-22-8) → 5-methyl-2-furfuryl acetate (18091-24-2)

Guidance literature:

With cobalt(II) sulphate heptahydrate; at 170 ℃; for 2h; under 22502.3 Torr; Inert atmosphere; Autoclave;

DOI:10.1039/d0cy00225a

Reference yield: 5.6%

2,3,4,5,6-pentahydroxy-hexanal (50-99-7,59-23-4,921-60-8,1949-88-8,1990-29-0,2152-76-3,2595-97-3,2595-98-4,3458-28-4,4205-23-6,5934-56-5,5978-95-0,5987-68-8,6027-89-0,6038-51-3,7635-11-2,10030-80-5,15572-79-9,19163-87-2,23567-25-1,26566-61-0,30077-17-9,31103-86-3,39665-52-6,40866-07-7,58367-01-4,58407-05-9,58407-06-0,83198-69-0,83198-70-3,83198-71-4,93780-23-5,145920-48-5) + acetic acid (64-19-7,77671-22-8) → 5-methyl-2-furfuryl acetate (18091-24-2)

Guidance literature:

With cobalt(II) sulphate heptahydrate; at 170 ℃; for 2h; under 22502.3 Torr; Inert atmosphere; Autoclave;

DOI:10.1039/d0cy00225a

Reference yield:

2-hydroxymethyl-5-methylfuran (3857-25-8) + acetic anhydride (108-24-7) → 5-methyl-2-furfuryl acetate (18091-24-2)

Guidance literature:

With sodium acetate;

upstream raw materials:

N,N-dimethyl-1-(5-methylfuran-2-yl)methanamine

acetic anhydride

2-hydroxymethyl-5-methylfuran

ethyl-dimethyl-(5-methyl-furfuryl)-ammonium; bromide

Downstream raw materials:

2,5-dimethylfuran

C₁₈H₂₀O₇S

Refernces

• 1、 Galkin, Konstantin I.,Ananikov, Valentine P.. "Towards Improved Biorefinery Technologies: 5-Methylfurfural as a Versatile C6 Platform for Biofuels Development". . p. 185 - 189. Retrieved 2018/12/05.