2-Cyclohexen-1-one, 3-[2-(3-furanyl)ethyl]-4-methyl-, (R)-

Base Information

Chemical Name:2-Cyclohexen-1-one, 3-[2-(3-furanyl)ethyl]-4-methyl-, (R)-
CAS No.:183620-23-7
Molecular Formula:C13H16O2
Molecular Weight:204.269
Hs Code.:
DSSTox Substance ID:DTXSID701191192

Synonyms:DTXSID701191192;2-Cyclohexen-1-one, 3-[2-(3-furanyl)ethyl]-4-methyl-, (R)-;183620-23-7

Suppliers and Price of 2-Cyclohexen-1-one, 3-[2-(3-furanyl)ethyl]-4-methyl-, (R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-Cyclohexen-1-one, 3-[2-(3-furanyl)ethyl]-4-methyl-, (R)-

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:204.115029749
Heavy Atom Count:15
Complexity:268

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1CCC(=O)C=C1CCC2=COC=C2
Isomeric SMILES:C[C@@H]1CCC(=O)C=C1CCC2=COC=C2

Technology Process of 2-Cyclohexen-1-one, 3-[2-(3-furanyl)ethyl]-4-methyl-, (R)-

There total 13 articles about 2-Cyclohexen-1-one, 3-[2-(3-furanyl)ethyl]-4-methyl-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 183620-22-6
[(3S,4R)-3-(2-Furan-3-yl-ethyl)-4-methyl-cyclohex-1-enyloxy]-trimethyl-silane

: 183620-23-7
(4R)-(+)-3-[2-(3-furyl)ethyl]-4-methylcyclohex-2-en-1-one

Guidance literature:: With palladium diacetate; In acetonitrile; for 3h;
DOI:10.1016/0957-4166(96)00371-0

Reference yield:

: 53616-34-5
2-(furan-3-yl)ethan-1-ol

: 183620-23-7
(4R)-(+)-3-[2-(3-furyl)ethyl]-4-methylcyclohex-2-en-1-one

Guidance literature:: Multi-step reaction with 4 steps

1: 76 percent / CBr₄, PPh₃ / CH₂Cl₂

2: Mg Rieke / tetrahydrofuran

3: 1.) CuI, 2.) Et₃N / 1.) -10 deg C, 2.) -40 deg C

4: 60 percent / Pd(OAc)2 / acetonitrile / 3 h

With palladium diacetate; copper(l) iodide; carbon tetrabromide; Mg Rieke; triethylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1016/0957-4166(96)00371-0

Reference yield:

: 14497-29-1
3-(chloromethyl)furan

: 183620-23-7
(4R)-(+)-3-[2-(3-furyl)ethyl]-4-methylcyclohex-2-en-1-one

Guidance literature:: Multi-step reaction with 7 steps

1: 97 percent / dimethylsulfoxide

2: 80 percent / KOH / methanol / Heating

3: 97 percent / LiAlH₄ / diethyl ether

4: 76 percent / CBr₄, PPh₃ / CH₂Cl₂

5: Mg Rieke / tetrahydrofuran

6: 1.) CuI, 2.) Et₃N / 1.) -10 deg C, 2.) -40 deg C

7: 60 percent / Pd(OAc)2 / acetonitrile / 3 h

With palladium diacetate; potassium hydroxide; copper(l) iodide; lithium aluminium tetrahydride; carbon tetrabromide; Mg Rieke; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; dimethyl sulfoxide; acetonitrile;
DOI:10.1016/0957-4166(96)00371-0