Triethyl(heptyl)silane

Base Information

• Chemical Name: Triethyl(heptyl)silane
• CAS No.: 18414-81-8
• Molecular Formula: C13H30Si
• DSSTox Substance ID: DTXSID80576298
• Nikkaji Number: J404.100C
• Wikidata: Q82465902
• Mol file: 18414-81-8.mol

Synonyms:TRIETHYL(HEPTYL)SILANE;18414-81-8;DTXSID80576298

Chemical Property of Triethyl(heptyl)silane

Chemical Property:

• Vapor Pressure: 0.049mmHg at 25°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 214.211677491
• Heavy Atom Count: 14
• Complexity: 108

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC[Si](CC)(CC)CC

Technology Process of Triethyl(heptyl)silane

There total 6 articles about Triethyl(heptyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

triethylsilyl chloride (994-30-9) + n-heptylmagnesium bromide (13125-66-1) → heptyltriethylsilane (18414-81-8)

Guidance literature:

In not given;

DOI:10.1021/ja01207a035

Reference yield:

triethylsilane (617-86-7) + 1-Heptene (592-76-7) → heptyltriethylsilane (18414-81-8) + Triethyl-((E)-hept-2-enyl)-silane (67963-89-7) + 1-(triethylsilyl)-1-heptene (79643-96-2)

Guidance literature:

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; In 1,2-dichloro-ethane; at 40 ℃; for 4h;

DOI:10.1039/c39810000673

Reference yield:

triethylsilane (617-86-7) + 1-Heptene (592-76-7) → heptyltriethylsilane (18414-81-8)

Guidance literature:

dihydrogen hexachloroplatinate; In tetrahydrofuran; at 100 ℃; for 4h;

upstream raw materials:

triethylsilane

1-Heptene

triethylsilyl chloride

n-heptylmagnesium bromide

Refernces

• 1、 Azpeitia, Susan,Garralda, María A.,Huertos, Miguel A.. "Rhodium(III) Catalyzed Solvent-Free Tandem Isomerization–Hydrosilylation From Internal Alkenes to Linear Silanes". . p. 1901 - 1905. Retrieved 2017/06/13.
• 2、 Millan, Andres,Towns, Elizabeth,Maitlis, Peter M.. "The Direct Conversion of α-Olefins into Vinyl- and Allyl-silanes catalysed by Rhodium Complexes". . p. 673 - 674. Retrieved 2007/10/02.