3-Heptafluorobutyryl-(+)-camphor

Base Information

Chemical Name:3-Heptafluorobutyryl-(+)-camphor
CAS No.:51800-99-8
Molecular Formula:C14H15 F7 O2
Molecular Weight:348.261
Hs Code.:2914700090
European Community (EC) Number:257-430-9
DSSTox Substance ID:DTXSID80880448
Nikkaji Number:J294.917B
Mol file:51800-99-8.mol

Synonyms:51800-99-8;3-Heptafluorobutyryl-(+)-camphor;EINECS 257-430-9;(1R)-3-(2,2,3,3,4,4,4-Heptafluoro-1-oxobutyl)-1,7,7-trimethylbicyclo(2.2.1)heptan-2-one;3-(Heptafluorobutyryl)-D-camphor;(1R,4R)-3-(2,2,3,3,4,4,4-heptafluorobutanoyl)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one;(1R,4R)-3-(Heptafluorobutyryl)-camphor;3-Heptafluorobutyryl-D-camphor;3-(Perfluorobutyryl)-(+)-camphor;(+)-3-(Heptafluorobutyryl)-(+)-camphor;3-(Perfluorobutyryl)-D-camphor;(1R)-3-(2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one;DTXSID80880448;C14H15F7O2;AKOS015913655;3-(Perfluorobutyryl)-(+)-camphor, 96%;(1R,4R)-3-(Heptafluorobutyryl)bornane-2-one;Bicyclo(2.2.1)heptan-2-one, 3-(2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)-1,7,7-trimethyl-, (1R)-

Suppliers and Price of 3-Heptafluorobutyryl-(+)-camphor

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3-(Perfluorobutyryl)-(+)-camphor 96%
5g
$ 115.00

Chem-Impex
3-(Perfluorobutyryl)-(+)-camphor,96%(Assay) 96%(Assay)
5G
$ 116.48

American Custom Chemicals Corporation
3-HEPTAFLUOROBUTYRYL-D-CAMPHOR 95.00%
1G
$ 662.40

AHH
3-Heptafluorobutyryl-D-camphor 97%
50g
$ 300.00

Total 11 raw suppliers

Chemical Property of 3-Heptafluorobutyryl-(+)-camphor

Chemical Property:

Vapor Pressure:0.00842mmHg at 25°C
Refractive Index:n20/D 1.421(lit.)
Boiling Point:266.9°Cat760mmHg
PKA:7.94±0.60(Predicted)
Flash Point:93.9°C
PSA：34.14000
Density:1.352g/cm³
LogP:4.02980
XLogP3:4.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:9
Rotatable Bond Count:3
Exact Mass:348.09602685
Heavy Atom Count:23
Complexity:564

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-(Perfluorobutyryl)-(+)-camphor 96% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC1(C2CCC1(C(=O)C2C(=O)C(C(C(F)(F)F)(F)F)(F)F)C)C
Isomeric SMILES:C[C@@]12CC[C@@H](C1(C)C)C(C2=O)C(=O)C(C(C(F)(F)F)(F)F)(F)F
Uses 3-(Perfluorobutyryl)-(+)-camphor can be used:As a ligand in the synthesis of chiral europium complex for optoelectronic and photonic applications.As a ligand in the preparation of sodium tetrakis(3-heptafluorobutylryl-(+)-camphorato) Ln(III) complexes applicable as chemical sensors and NMR shift reagents.

Technology Process of 3-Heptafluorobutyryl-(+)-camphor

There total 1 articles about 3-Heptafluorobutyryl-(+)-camphor which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 375-16-6
heptafluorobutyryl chloride

: 464-49-3,68546-28-1
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 51800-99-8,115224-00-5
(+)-3-heptafluorobutanoylcampher

Guidance literature:: Multistep reaction; (i) NaH, 1,2-dimethoxy-ethane, (heating), (ii) /BRN= 1790269/;
DOI:10.1021/ja00812a036

Reference yield:

: uranyl acetate

: 51800-99-8,115224-00-5
(+)-3-heptafluorobutanoylcampher

: [UO₂(C₁₄H₁₄F₇O₂)2]

Guidance literature:: With sodium hydride; In methanol; toluene; byproducts: H2; (N2); addn. of the ligand in toluene to NaH, stirring (30 min), filtration, evapn. (reduced pressure), dissoln. (MeOH), addn. of UO2(Ac)2 in MeOH, stirring (20°C, 2 h, reflux, 30 min); evapn. (vac.), dissoln. (n-hexane), filtration (Celite), washing (H2O), drying (Na2SO4), evapn. (50°C, vac.);
DOI:10.1002/cber.19971300711

Reference yield:

: europium(III) chloride hexahydrate

: 51800-99-8,115224-00-5
(+)-3-heptafluorobutanoylcampher

: 93-91-4
1-phenylbutan-1,3-dione

: Eu(OC(CH₃)CHC(C₆H₅)O)2(OC(C₃F₇)C₉H₁₄C(O))(H₂O)

Guidance literature:: With sodium hydroxide; In ethanol; water; Eu-salt dissolved in EtOH, chiral organic compound and achiral organic compound in molar ratio 1:2 dissolved in a 50/50 mixture of EtOH/H2O and NaOH added, Eu-soln. poured into diketone soln., stirred for few min; filtered, washed with distilled water, dried at 80°C for 1.5 h; elem. anal.;
DOI:10.1016/0022-1902(81)80270-9