acetonitrile,[3-diphenylphosphanyl-2-(diphenylphosphanylmethyl)-2-methyl-propyl]-diphenyl-phosphane,ruthenium(+2) cation,trifluoromethanesulfonate

Base Information

Chemical Name:acetonitrile,[3-diphenylphosphanyl-2-(diphenylphosphanylmethyl)-2-methyl-propyl]-diphenyl-phosphane,ruthenium(+2) cation,trifluoromethanesulfonate
CAS No.:103500-16-9
Molecular Formula:C49H48F6N3O6P3RuS2
Molecular Weight:1147.05
Hs Code.:
Mol file:103500-16-9.mol

acetonitrile,[3-diphenylphosphanyl-2-(diphenylphosphanylmethyl)-2-methyl-propyl]-diphenyl-phosphane,ruthenium(+2) cation,trifluoromethanesulfonate

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of acetonitrile,[3-diphenylphosphanyl-2-(diphenylphosphanylmethyl)-2-methyl-propyl]-diphenyl-phosphane,ruthenium(+2) cation,trifluoromethanesulfonate

Chemical Property:

Vapor Pressure:3.5E-19mmHg at 25°C
Boiling Point:709.9°Cat760mmHg
Flash Point:409.6°C
Density:g/cm³

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of acetonitrile,[3-diphenylphosphanyl-2-(diphenylphosphanylmethyl)-2-methyl-propyl]-diphenyl-phosphane,ruthenium(+2) cation,trifluoromethanesulfonate

There total 3 articles about acetonitrile,[3-diphenylphosphanyl-2-(diphenylphosphanylmethyl)-2-methyl-propyl]-diphenyl-phosphane,ruthenium(+2) cation,trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 103500-17-0
[tris(μ-chloro)bis((triphos)ruthenium(II))] chloride

: 2923-28-6
silver trifluoromethanesulfonate

: 75-05-8,26809-02-9
acetonitrile

: 103500-16-9
[(MeC(CH₂PPh₂)3)Ru(acetonitrile)3](CF₃SO₃)2

Guidance literature:: at 20 ℃; for 6h; Inert atmosphere; Reflux;

Reference yield: 92.0%

: 103500-17-0
[tris(μ-chloro)bis((triphos)ruthenium(II))] chloride

: 2923-28-6
silver trifluoromethanesulfonate

: 103500-16-9
[(MeC(CH₂PPh₂)3)Ru(acetonitrile)3](CF₃SO₃)2

Guidance literature:: With MeCN; In acetonitrile; byproducts: AgCl; Ar atmosphere, refluxing (3-4 h); filtration (Celite, AgCl removal), vol. redn., pptn. (toluene addn.), washing (toluene, Et2O), drying; elem. anal.;

Reference yield: 76.5%

: 169334-49-0
Ru(CF₃COO)2(CH₃C(CH₂P(C₆H₅)2)3)

: 1493-13-6
trifluorormethanesulfonic acid

: 75-05-8,26809-02-9
acetonitrile

: 103500-16-9
[(MeC(CH₂PPh₂)3)Ru(acetonitrile)3](CF₃SO₃)2

Guidance literature:: In acetonitrile; Ar-atmosphere; dropwise addn. of 4 equiv. CF3SO3H to Ru-complex soln. atroom temp., stirring (room temp., 1 h); concn. (reduced pressure), pptn. on Et2O addn., decantation, washing (Et2O), stirring with Et2O, filtration, washing (Et2O), drying (vac.); elem. anal.;