Silane, (1,2-diphenyl-1,2-ethanediyl)bis[trimethyl-

Base Information

• Chemical Name: Silane, (1,2-diphenyl-1,2-ethanediyl)bis[trimethyl-
• CAS No.: 18586-58-8
• Molecular Formula: C20H30Si2
• Molecular Weight: 326.629
• DSSTox Substance ID: DTXSID40451471
• Nikkaji Number: J695.083C
• Mol file: 18586-58-8.mol

Synonyms:Silane, (1,2-diphenyl-1,2-ethanediyl)bis[trimethyl-;18586-58-8;DTXSID40451471;1,2-Bis(trimethylsilyl)-1,2-diphenylethane

Chemical Property of Silane, (1,2-diphenyl-1,2-ethanediyl)bis[trimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 326.18860403
• Heavy Atom Count: 22
• Complexity: 291

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C(C1=CC=CC=C1)C(C2=CC=CC=C2)[Si](C)(C)C

Technology Process of Silane, (1,2-diphenyl-1,2-ethanediyl)bis[trimethyl-

There total 25 articles about Silane, (1,2-diphenyl-1,2-ethanediyl)bis[trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

3-Phenyl-3-(trimethylsilyl)propylbromidm (109153-90-4) → 1,2-bis(trimethylsilyl)-1,2-diphenylethane (18586-58-8) + 3-Phenyl-3-(trimethylsilyl)propyllithium (109153-93-7) + C24H38Si2 (109154-06-5)

Guidance literature:

With lithium; In various solvent(s); at -30 ℃; Product distribution; Thermodynamic data; oter solvent D8-THF/ether-D10, other temp; ΔG(excit.);

Reference yield: 53.0%

benzoyltrimethylsilane (5908-41-8) → 1,2-bis(trimethylsilyl)-1,2-diphenylethane (18586-58-8) + (E)-α,β-bis(trimethylsilyl)stilbene (24894-87-9)

Guidance literature:

With aluminum oxide; titanium(III) chloride; sodium; In tetrahydrofuran; at 65 ℃; for 5h;

DOI:10.1016/0040-4020(95)00482-N

Reference yield: 21.0%

phenyl(trimethylsilyl)methyl bromide (17903-41-2) → threo-1,2-diphenyl-1,2-bis(trimethylsilyl)ethane (24894-88-0) + erythro-1,2-diphenyl-1,2-bis(trimethylsilyl)ethane (18586-58-8,24894-88-0,62120-71-2) + 1-(Phenyl-trimethylsilanyl-methyl)-4-trimethylsilanylmethyl-benzene + 1-(Phenyl-trimethylsilanyl-methyl)-2-trimethylsilanylmethyl-benzene

Guidance literature:

In acetonitrile; for 36h; electrolysis at -1.2 V;

DOI:10.1021/jo951577f

upstream raw materials:

3-Phenyl-3-(trimethylsilyl)propylbromidm

Diphenylmethane

phenyl(trimethylsilyl)methyl bromide

1,1-bis(trimethylsilyl)-1,2-diphenylethane

Downstream raw materials:

2,2-diphenylacetaldehyde dimethyl acetal

(1R,2S)-1,2-dimethoxy-1,2-diphenylethane

(+/-)-1,2-dimethoxy-1,2-diphenylethane

1,2-diphenyl-1,2-dimethoxy ethane, meso