17903-41-2Relevant articles and documents
A general synthesis of β-silylallenes from allylsilanes
Lahrech, Mokhtar,Hacini, Salih,Parrain, Jean-Luc,Santelli, Maurice
, p. 3395 - 3398 (1997)
β-Trimethylsilyl allenes have been prepared in fair to good yields from allylsilanes by successive dibromocarbene addition and rearrangement of the cyclopropylidenes. In the case of 3,6-bis(trimethylsilyl)cyclohexa-1,4-diene, insertion of dibromocarbene o
Saturated abnormal NHC-gold(I) complexes: Synthesis and catalytic activity
Manzano, Ruben,Rominger, Frank,Hashmi, A. Stephen K.
supporting information, p. 2199 - 2203 (2013/05/21)
New saturated abnormal N-heterocyclic carbene complexes of gold(I) have been prepared by a 1,3-dipolar cycloaddition of an in situ generated azomethine ylide with an isocyanogold(I) choride. A series of different substituents on the nitrogen atom of the 1
Novel generation of azomethine imines from α-silylnitrosamines by 1,4- silatropic shift and their cycloaddition
Washizuka, Ken-Ichi,Nagai, Keiko,Minakata, Satoshi,Ryu, Ilhyong,Komatsu, Mitsuo
, p. 8849 - 8853 (2007/10/03)
Novel and facile generation of azomethine imines from α- silylnitrosamines and subsequent cycloaddition with dipolarophiles leading to a variety of pyrazole derivatives have been developed. The key to the reaction is a 1,4-silatropic shift caused by stron
