Stannylene, bis(2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-yl)-

Base Information

• Chemical Name: Stannylene, bis(2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-yl)-
• CAS No.: 188685-27-0
• Molecular Formula: C48H50Sn
• Molecular Weight: 745.635
• Mol file: 188685-27-0.mol

Synonyms:

Chemical Property of Stannylene, bis(2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-yl)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannylene, bis(2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-yl)-

There total 4 articles about Stannylene, bis(2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.5%

(2,6-dimesitylphenyl)lithium + tin(ll) chloride → Sn(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2 (188685-27-0)

Guidance literature:

In diethyl ether; N2-atmosphere; stirring (0°C, 30 min, room temp., 4 h); evapn. (reduced pressure), extg. (toluene), filtering, crystn. on concg.(-20°C, 30 h); elem. anal.;

DOI:10.1021/om960929l

Reference yield:

C50H56SnZn → Sn(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2 (188685-27-0) + dimethyl zinc(II) (544-97-8)

Guidance literature:

In benzene-d6; at 25 ℃; Temperature; Equilibrium constant; Thermodynamic data;

DOI:10.1021/acs.organomet.6b00344

Reference yield:

(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2Sn(Et)GaEt2 → Sn(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2 (188685-27-0) + triethyl gallium (1115-99-7)

Guidance literature:

In toluene; at 20 ℃;

DOI:10.1021/ic502824w

Downstream raw materials:

Sn(C₆H₃(C₆H₂(CH₃)3)2)2(OH)2

C₄₈H₅₁FSn

C₄₈H₅₃PSn

2,4,6,2'',4'',6''-hexamethyl-1,1':3',1''-terphenyl