Ethylmercury hydroxide

Base Information

• Chemical Name: Ethylmercury hydroxide
• CAS No.: 107-28-8
• Molecular Formula: C₂H₆HgO
• Molecular Weight: 246.659
• UNII: X3N9D01L1W
• Mol file: 107-28-8.mol

Synonyms:ETHYLMERCURY HYDROXIDE

Chemical Property of Ethylmercury hydroxide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 248.012508
• Heavy Atom Count: 4
• Complexity: 2.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Hg+].[OH-]

Technology Process of Ethylmercury hydroxide

There total 4 articles about Ethylmercury hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8-quinolinol (148-24-3,24804-14-6) + ethylmercury (1+); bromide (107-26-6) → ethylmercury (1+); hydroxide (107-28-8) + C2H5(1-)*Hg(2+)*C9H6NO(1-)=C2H5Hg(C9H6NO)

Guidance literature:

With Ag₂O; NaOH; NaH₂PO₄; In water; benzene; byproducts: AgBr; to aq. suspn. of EtHgBr added 1.5 equiv. of freshly prepd. Ag2O, stirred for several days, solid NaOH added up to 0.1 M, left to stand overnight, filtered, neutralized with HClO4, NaH2PO4, Na2HPO4 and 8-quinolinol (C6H6) added, dild., shaken for 30 min; org. layer analyzed by means of spectrophotometry;

DOI:10.1246/bcsj.57.2271

Reference yield:

8-quinolinol (148-24-3,24804-14-6) + ethylmercury (1+); bromide (107-26-6) → C2H5(1-)*Hg(2+)*CH3COO(1-)=C2H5Hg(CH3COO) + C2H5(1-)*Hg(2+)*C9H6NO(1-)*OH(1-)=[C2H5Hg(C9H6NO)(OH)](1-) + C2H5(1-)*Hg(2+)*OH(1-)*CH3COO(1-)=[C2H5Hg(OH)(CH3COO)](1-) + ethylmercury (1+); hydroxide (107-28-8) + C2H5(1-)*Hg(2+)*C9H6NO(1-)=C2H5Hg(C9H6NO)

Guidance literature:

With sodium hydroxide; acetic acid; silver(l) oxide; In ethanol; water; byproducts: AgBr; to aq. suspn. of EtHgBr added 1.5 equiv. of freshly prepd. Ag2O, stirred for several days, solid NaOH added up to 0.1 M, left to stand overnight, filtered, neutralized with HClO4, AcOH, AcONa, NaClO4, and 8-quinolinol (EtOH) added, dild., kept for 1.5 h; analyzed by means of spectrophotometric and pH measurements;

DOI:10.1246/bcsj.57.2266

Reference yield:

diethylmercury (627-44-1) → ethylmercury (1+); hydroxide (107-28-8)

Guidance literature:

upstream raw materials:

diethylmercury

ethanol

ethylmercury(II) chloride

8-quinolinol

Downstream raw materials:

4-chloro-3-methyl-phenol; ethylmercury-(4-chloro-3-methyl-phenolate)

ethylmercury (1+); 2,3-dihydroxy-propane-1-thiolate