cis-VERBENOL

Base Information

• Chemical Name: cis-VERBENOL
• CAS No.: 1845-30-3
• Molecular Formula: C10H16 O
• Molecular Weight: 152.236
• Mol file: 1845-30-3.mol

Synonyms:2-Pinen-4-ol,cis- (8CI); Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl-, (1a,2b,5a)-; (?à)-cis-Verbenol; cis-Verbenol

Chemical Property of cis-VERBENOL

Chemical Property:

• Melting Point: 15.5°C
• Refractive Index: 1.4912 (estimate)
• Boiling Point: 234.73°C (rough estimate)
• PKA: 14.56±0.60(Predicted)
• PSA: 20.23000
• Density: 0.9684
• LogP: 1.96950

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cis-VERBENOL

There total 87 articles about cis-VERBENOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

Pinene (80-56-8,177698-18-9,25766-18-1) → verbenone (80-57-9) + Verbenol (1820-09-3,1845-30-3,5416-53-5,13040-03-4,18881-04-4,19890-02-9,22339-08-8,80795-83-1,473-67-6)

Guidance literature:

With oxygen; Enzymatic reaction;

DOI:10.1016/j.molcatb.2015.02.006

Reference yield: 29.0%

Pinene (80-56-8,177698-18-9,25766-18-1) → verbenone (80-57-9) + Verbenol (1820-09-3,1845-30-3,5416-53-5,13040-03-4,18881-04-4,19890-02-9,22339-08-8,80795-83-1,473-67-6) + pinocarveyl hydroperoxide (22321-84-2) + verbenyl-hydroperoxide (94268-68-5) + α-pinene epoxide (1686-14-2,25488-94-2)

Guidance literature:

With oxygen; at 89.84 ℃; under 750.075 Torr;

DOI:10.1002/cssc.200900228

Reference yield:

Pinene (80-56-8,177698-18-9,25766-18-1) → verbenone (80-57-9) + Verbenol (1820-09-3,1845-30-3,5416-53-5,13040-03-4,18881-04-4,19890-02-9,22339-08-8,80795-83-1,473-67-6) + pinocarveol (547-61-5,1674-08-4,2158-49-8,3917-59-7,5947-36-4,6712-79-4,19889-99-7,19894-98-5) + sobrerol (498-71-5,454-77-3,772-36-1,32226-54-3,38235-58-4,42370-41-2,54164-89-5,60687-00-5,71697-84-2)

Guidance literature:

With Acetobacter methanolicus MB 58; microbielle oxydation;

upstream raw materials:

Pinene

rac-α-pinene

dihydrogen peroxide

acetone

Downstream raw materials:

verbenone

4-methylisopropylbenzene

pinan-4-ol

6,6-dimethyl4-methylidenebicyclo[3.1.1]hept-2-ene