Perfluorotriethylamine

Base Information

• Chemical Name: Perfluorotriethylamine
• CAS No.: 359-70-6
• Molecular Formula: C6F15 N
• Molecular Weight: 371.049
• Hs Code.: 29211990
• European Community (EC) Number: 206-632-5
• DSSTox Substance ID: DTXSID40189464
• Nikkaji Number: J193.860F
• Wikidata: Q72515336
• Mol file: 359-70-6.mol

Synonyms:perfluorotriethylamine

Chemical Property of Perfluorotriethylamine

Chemical Property:

• Appearance/Colour: colorless, odorless, clear liquid
• Vapor Pressure: 2.15 psi ( 20 °C)
• Melting Point: -116.95°C
• Refractive Index: n20/D 1.262(lit.)
• Boiling Point: 70.3 °C at 760 mmHg
• PKA: -27.46±0.50(Predicted)
• PSA: 3.24000
• Density: 1.711 g/cm³
• LogP: 4.75370
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• XLogP3: 5.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 16
• Rotatable Bond Count: 3
• Exact Mass: 370.9791214
• Heavy Atom Count: 22
• Complexity: 334

Purity/Quality:

99% ^*data from raw suppliers

Perfluoro ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(C(F)(F)F)(N(C(C(F)(F)F)(F)F)C(C(F)(F)F)(F)F)(F)F
• Uses: Perfluorotriethylamine is used for toxicity test, cytotoxicity, genotoxicity and pyrolysis experiments.

Technology Process of Perfluorotriethylamine

There total 27 articles about Perfluorotriethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.2%

triethylamine (121-44-8) → perfluorotriethylamine (359-70-6)

Guidance literature:

With fluorine; sodium fluoride; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 5 ℃; for 5h;

DOI:10.1016/S0022-1139(03)00146-5

Reference yield: 31.2%

methyl 2-methyl-3-(N,N-diethylamino)propionate (31084-16-9,86685-74-7,86685-76-9) → perfluorotriethylamine (359-70-6) + heptafluoropropyl-bis-pentafluoroethyl-amine (338-81-8) + perfluoroisobutyryl fluoride (677-84-9) + 2-[[bis(1,1,2,2,2-pentafluoroethyl)amino]difluoromethyl]-2,3,3,3-tetrafluoropropanoyl fluoride (122531-25-3)

Guidance literature:

With hydrogen fluoride; at 7 - 8 ℃; for 10.2667h; electrochemical reaction; anodic current density of 3.5 A dm^-2, a cell voltage of 6.0 V - 6.1 V;

DOI:10.1016/0022-1139(93)03019-I

Reference yield: 30.1%

methyl 3-(N,N-diethylamino)propionate (5351-01-9) → perfluoropropanoyl fluoride (422-61-7) + perfluoro(N,N-diethylmethylamine) (758-48-5) + perfluorotriethylamine (359-70-6) + Perfluoro[3-(N,N-diethylamino)propionyl fluoride] (17235-62-0)

Guidance literature:

With hydrogen fluoride; at 7 - 8 ℃; for 8.68333h; electrochemical fluorination;

DOI:10.1016/S0022-1139(00)82821-3

upstream raw materials:

triethylamine

methyl 2-diethylamino-propionate

methyl 3-(N,N-diethylamino)propionate

tetraethylammonium iodide

Refernces

• 1、 Dimitrov, Anton,Ruediger, Stephan,Pauli, Jutta. "On the formation of surface active by-products during the electrochemical fluorination of tertiary amines". . p. 223 - 228. Retrieved 1994.
• 2、 Abe, Takashi,Baba, Hajime,Fukaya, Haruhiko,Tamura, Masanori,Sekiya, Akira. "Simons electrochemical fluorination of substituted homopiperazines(hexahydro-1,4-diazepines) and piperazines". . p. 27 - 38. Retrieved 2007/10/03.
• 3、 Abe, Takashi,Fukaya, Haruhiko,Hayashi, Eiji,Ono, Taizo,Nishida, Masakazu,Soloshonok, Irina,Okuhara, Kunio. "Electrochemical fluorination of (N,N-dialkylamino)alcohols". . p. 229 - 237. Retrieved 2007/10/03.