2,2'-Bipyridine, 4,4'-dimethyl-6,6'-diphenyl-

Base Information

• Chemical Name: 2,2'-Bipyridine, 4,4'-dimethyl-6,6'-diphenyl-
• CAS No.: 192863-71-1
• Molecular Formula: C24H20N2
• Molecular Weight: 336.436
• Mol file: 192863-71-1.mol

Synonyms:

Chemical Property of 2,2'-Bipyridine, 4,4'-dimethyl-6,6'-diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2'-Bipyridine, 4,4'-dimethyl-6,6'-diphenyl-

There total 2 articles about 2,2'-Bipyridine, 4,4'-dimethyl-6,6'-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

1,4,4'-trimethyl-6,6'-diphenyl-2,2'-bipyridinium triflate → 4,4’-dimethyl-6,6’-diphenyl-2,2’-bipyridine (192863-71-1)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In N,N-dimethyl-formamide; for 2h; Heating;

DOI:10.1002/ejic.200400418

Reference yield: 20.0%

4,4'-dimethyl-2,2'-bipyridines (1134-35-6) + phenyllithium (591-51-5) → 4,4’-dimethyl-6,6’-diphenyl-2,2’-bipyridine (192863-71-1)

Guidance literature:

With manganese(IV) oxide; In toluene;

DOI:10.1016/S0040-4039(97)00896-4

Reference yield: 81.0%

potassium hexafluorophosphate (17084-13-8) + cis-dichloridobis(1,10-phenanthroline)ruthenium(II) + 4,4’-dimethyl-6,6’-diphenyl-2,2’-bipyridine (192863-71-1) → [Ru(1,10-phenanthroline)(4,4'-dimethyl-6,6'-diphenyl-2,2'-bipyridine)](PF6)2

Guidance literature:

In ethylene glycol; Ar atmosphere, refluc of soln. of Ru complex and bipyridine (3 h), cooling to room temp., addn. of satd. aq. K(PF6); filtration, washing (water, Et2O), drying, chromy. (silica gel, CH2Cl2/MeOH (0-2%));

DOI:10.1002/(sici)1099-0682(199903)1999:3<383::aid-ejic383>3.0.co;2-9

upstream raw materials:

4,4'-dimethyl-2,2'-bipyridines

phenyllithium

Downstream raw materials:

C₄₈H₃₆N₄

C₄₆H₄₆N₄

Refernces

• 1、 Akdas-Kilig, Huriye,Malval, Jean-Pierre,Morlet-Savary, Fabrice,Singh, Anu,Toupet, Loic,Ledoux-Rak, Isabelle,Zyss, Joseph,Le Bozec, Hubert. "The synthesis of tetrahedral bipyridyl metallo-octupoles with large second- and third-order nonlinear optical properties". scheme or table. p. 681 - 688. Retrieved 2012/02/06.