Acetic acid, [(4-methoxyphenyl)imino]-, 2-propenyl ester

Base Information

• Chemical Name: Acetic acid, [(4-methoxyphenyl)imino]-, 2-propenyl ester
• CAS No.: 194099-83-7
• Molecular Formula: C₁₂H₁₃NO₃
• Molecular Weight: 219.24
• DSSTox Substance ID: DTXSID20455836
• Mol file: 194099-83-7.mol

Synonyms:194099-83-7;Acetic acid, [(4-methoxyphenyl)imino]-, 2-propenyl ester;DTXSID20455836

Chemical Property of Acetic acid, [(4-methoxyphenyl)imino]-, 2-propenyl ester

Chemical Property:

• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 219.08954328
• Heavy Atom Count: 16
• Complexity: 255

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)N=CC(=O)OCC=C

Technology Process of Acetic acid, [(4-methoxyphenyl)imino]-, 2-propenyl ester

There total 1 articles about Acetic acid, [(4-methoxyphenyl)imino]-, 2-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-methoxy-aniline (104-94-9) + allyl 2-oxoacetate (64370-42-9) → allyl (4-methoxyphenylimino)acetate (194099-83-7)

Guidance literature:

In toluene; at 20 ℃; Inert atmosphere; Molecular sieve;

DOI:10.1021/jo901291t

Reference yield:

allyl (4-methoxyphenylimino)acetate (194099-83-7) + isovaleraldehyde (590-86-3) → allyl (2S,3R)-3-formyl-2-(p-methoxyphenylamino)-4-methylpentanoate + allyl 3-formyl-2-(p-methoxyphenylamino)-4-methylpentanoate

Guidance literature:

With N-(4,5-dihydro-3H-4-aza-cyclohepta[2,1-a;3,4-a']dinaphthalen-2-yl)-C,C,C-trifluoro-methanesulfonamide; In 1,4-dioxane; at 20 ℃; for 0.5h; optical yield given as %ee; enantioselective reaction;

DOI:10.1002/chem.200900267

upstream raw materials:

4-methoxy-aniline

allyl 2-oxoacetate