Tetrabutylammonium tetrafluoroborate

Base Information

• Chemical Name: Tetrabutylammonium tetrafluoroborate
• CAS No.: 429-42-5
• Molecular Formula: C16H36BF4N
• Molecular Weight: 329.273
• Hs Code.: 29239000
• European Community (EC) Number: 207-058-8
• DSSTox Substance ID: DTXSID7059983
• ChEMBL ID: CHEMBL1078071
• Mol file: 429-42-5.mol

Synonyms:NBu4 BF4;tetrabutylammonium tetrafluoroborate

Chemical Property of Tetrabutylammonium tetrafluoroborate

Chemical Property:

• Appearance/Colour: white crystalline powder
• Melting Point: 155-161 °C
• Flash Point: >93℃
• PSA: 0.00000
• LogP: 6.30360
• Storage Temp.: −20°C
• Sensitive.: Hygroscopic
• Solubility.: methanol: 0.1 g/mL, clear, colorless
• Water Solubility.: Slightly soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 12
• Exact Mass: 329.2876930
• Heavy Atom Count: 22
• Complexity: 135

Purity/Quality:

99% ^*data from raw suppliers

Tetrabutylammonium tetrafluoroborate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,T
• Hazard Codes: Xi,T,Xn
• Statements: 36/37/38-41-37/38-22
• Safety Statements: 26-36-37/39-39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Quaternary Amines
• Canonical SMILES: [B-](F)(F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC
• Uses: Tetrabutylammonium tetrafluoroborate may be used in the following studies: As supporting electrolyte in the voltammetric determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC). Synthesis of biologically relevant macrolactones, Sansalvamide A. As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry. Preparation of 1:1 adduct with 1,10-phenanthroline.Used to prepare other tetrabutylammonium salts in aqueous solutions. As electrolyte additive in the synthesis of conducting poly(thiophenes). TBATFB has been used as an electrolyte to understand the paraffin graphite powder modified with sweet potato tissue (PCPET) electrode response.

Technology Process of Tetrabutylammonium tetrafluoroborate

There total 76 articles about Tetrabutylammonium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

tetrabutylammomium bromide (1643-19-2) → tetrabutylammonium tetrafluoroborate (429-42-5)

Guidance literature:

With potassium tetrafluoroborate; In dichloromethane; water; at 20 ℃; for 24h;

Reference yield: 96.0%

tetrabutylammomium bromide (1643-19-2) + potassium tetrafluoroborate (14075-53-7) → tetrabutylammonium tetrafluoroborate (429-42-5)

Guidance literature:

In dichloromethane; water; at 20 ℃; for 24h;

Reference yield: 96.0%

sodium tetrafluoroborate (13755-29-8) + tetrabutylammomium bromide (1643-19-2) → tetrabutylammonium tetrafluoroborate (429-42-5)

Guidance literature:

In dichloromethane; water;

upstream raw materials:

tetrabutylammonium acetate

tetrabutylammonium 3,5-dinitrobenzoate

tetrabutylammonium 4-nitrobenzoate

Downstream raw materials:

tetrabutylammonium benzoate

tetrabutylammonium 4-nitrobenzoate

tetrabutylammonium 3,5-dinitrobenzoate

tetrabutylammonium acetate

Refernces

• 1、 Yurko,Gryaznova,Kholin,Khrizanforova,Budnikova. "External oxidant-free cross-coupling: Electrochemically induced aromatic C-H phosphonation of azoles with dialkyl-: H -phosphonates under silver catalysis". . p. 190 - 196. Retrieved 2018.
• 2、 Gusain, Rashi,Khatri, Om P.. "Halogen-free ionic liquids: Effect of chelated orthoborate anion structure on their lubrication properties". . p. 25287 - 25294. Retrieved 2015.
• 3、 Lowe, Nigel D.,Garner, C. David. "Transition-metal Complexes of Crown Ether Benzodithiolenes. Part 2. The Effects of Alkali-metal Cation Binding". . p. 3333 - 3340. Retrieved 1993.
• 4、 Bond, Andrew D.,Goodman, Jonathan M.,Lee, Sanha,Plajer, Alex J.,Wright, Dominic S.. "Charge-Assisted phosph(v)azane anion receptors". . p. 3403 - 3407. Retrieved 2020/04/02.