Stannin, hexahydro-1,1-diphenyl-

Base Information

• Chemical Name: Stannin, hexahydro-1,1-diphenyl-
• CAS No.: 19814-46-1
• Molecular Formula: C17H20Sn
• Molecular Weight: 343.056
• Mol file: 19814-46-1.mol

Synonyms:

Chemical Property of Stannin, hexahydro-1,1-diphenyl-

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannin, hexahydro-1,1-diphenyl-

There total 6 articles about Stannin, hexahydro-1,1-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,5-bis(triphenylstannyl)pentane (5588-71-6) → tetraphenyltin(IV) (595-90-4) + 1,1-diphenylstannacyclohexane (19814-46-1)

Guidance literature:

With zinc(II) chloride;

Reference yield:

1,5-bis(triphenylstannyl)pentane (5588-71-6) + (C6H5)ClSn(CH2)5 (82744-03-4) → tetraphenyltin(IV) (595-90-4) + 1,1-diphenylstannacyclohexane (19814-46-1)

Guidance literature:

Reference yield:

1,5-dibromo-pentane (111-24-0) + diphenyltin(IV) dichloride (1135-99-5) + magnesium (7439-95-4) → 1,1-diphenylstannacyclohexane (19814-46-1)

Guidance literature:

With HCl; In diethyl ether; addn. of 1,5-dibromopentane in dry ether to Mg turnings, slow addn. of diphenyl tin dichloride in dry ether (room temp.), refluxing (3 h), cooling, hydrolysis by pouring in ice-cold 1M HCl; decanting of organic layer, washing (10% KF soln.), decanting, drying (MgSO4), removing of solvent, distn. of residual oil (395-398 K, 13 Pa); elem. anal.;

DOI:10.1016/0021-9614(88)90220-0

upstream raw materials:

1,5-bis(triphenylstannyl)pentane

(C₆H₅)ClSn(CH₂)5

(C₆H₅)ClSn(CH₂)4

1,4-bis(triphenylstannyl)butane

Downstream raw materials:

(C₆H₅)ClSn(CH₂)5

1,5-bis(triphenylstannyl)pentane

bromobenzene

1,1-dibromo-1-stannacyclohexane

Refernces