(4-Dodecylphenyl)boronic acid

Base Information

Chemical Name:(4-Dodecylphenyl)boronic acid
CAS No.:206763-93-1
Molecular Formula:C18H31BO2
Molecular Weight:290.254
Hs Code.:
DSSTox Substance ID:DTXSID60592552
Nikkaji Number:J2.385.847I
Wikidata:Q82486720

Synonyms:(4-Dodecylphenyl)boronic acid;206763-93-1;Boronic acid, B-(4-dodecylphenyl)-;(4-Dodecylphenyl)boronicacid;SCHEMBL1020214;C18H31BO2;DTXSID60592552;4-DODECYLPHENYLBORONIC ACID;MFCD28969070;AKOS030568736;DS-19748;CS-0158103;C73917

Suppliers and Price of (4-Dodecylphenyl)boronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of (4-Dodecylphenyl)boronic acid

Chemical Property:

Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:12
Exact Mass:290.2417104
Heavy Atom Count:21
Complexity:225

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=C(C=C1)CCCCCCCCCCCC)(O)O

Technology Process of (4-Dodecylphenyl)boronic acid

There total 5 articles about (4-Dodecylphenyl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 121-43-7,63156-11-6
Trimethyl borate

: 126930-72-1
1-bromo-4-dodecylbenzene

: 7732-18-5
water

: 206763-93-1
(4-dodecylphenyl)boronic acid

Guidance literature:: 1-bromo-4-dodecylbenzene; With magnesium; In tetrahydrofuran; at 20 ℃; for 1h;

Trimethyl borate; In tetrahydrofuran; for 0.5h; Cooling with ice;

water; With hydrogenchloride; In tetrahydrofuran; at 20 ℃; for 0.5h;

Reference yield:

: 5419-55-6
Triisopropyl borate

: 126930-72-1
1-bromo-4-dodecylbenzene

: 206763-93-1
(4-dodecylphenyl)boronic acid

Guidance literature:: 1-bromo-4-dodecylbenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -50 ℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique;

Triisopropyl borate; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere; Glovebox; Schlenk technique;

With hydrogenchloride; In tetrahydrofuran; hexane; water; for 1h; Inert atmosphere; Glovebox; Schlenk technique;
DOI:10.1002/chem.201703902

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 206763-93-1
(4-dodecylphenyl)boronic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: aluminum (III) chloride / 1 h / 50 °C / Inert atmosphere; Glovebox; Schlenk technique

2.1: potassium hydroxide; hydrazine / 2,2'-[1,2-ethanediylbis(oxy)]bisethanol / 6 h / 170 - 230 °C / Inert atmosphere; Glovebox; Schlenk technique

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -50 °C / Inert atmosphere; Glovebox; Schlenk technique

3.2: 20 °C / Inert atmosphere; Glovebox; Schlenk technique

3.3: 1 h / Inert atmosphere; Glovebox; Schlenk technique

With aluminum (III) chloride; n-butyllithium; potassium hydroxide; hydrazine; In tetrahydrofuran; hexane; 2,2'-[1,2-ethanediylbis(oxy)]bisethanol;
DOI:10.1002/chem.201703902