Chlorotris[(4-fluorophenyl)methyl]stannane

Base Information

Chemical Name:Chlorotris[(4-fluorophenyl)methyl]stannane
CAS No.:2069-76-3
Molecular Formula:C21H18ClF3Sn
Molecular Weight:481.532
Hs Code.:
DSSTox Substance ID:DTXSID60504817
Wikidata:Q82359567

Synonyms:Chlorotris[(4-fluorophenyl)methyl]stannane;2069-76-3;DTXSID60504817

Suppliers and Price of Chlorotris[(4-fluorophenyl)methyl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Chlorotris[(4-fluorophenyl)methyl]stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:482.007115
Heavy Atom Count:26
Complexity:352

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC=C1C[Sn](CC2=CC=C(C=C2)F)(CC3=CC=C(C=C3)F)Cl)F

Technology Process of Chlorotris[(4-fluorophenyl)methyl]stannane

There total 1 articles about Chlorotris[(4-fluorophenyl)methyl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

: 7440-31-5
tin

: 352-11-4
1-chloromethyl-4-fluorobenzene

: 2069-76-3
tris(p-fluorobenzyl)tin chloride

Guidance literature:: tin(ll) chloride; In propan-1-ol; (N2); excess of tin; refluxed for 3 h with vigourous stirring; hot filtered, poured into benzene/aq.HCl, decanted, org. phase washed (acidified H2O), dried, evapd., recrystd. (ethyl acetate); elem. anal.;

Reference yield: 86.0%

: 2069-76-3
tris(p-fluorobenzyl)tin chloride

: 1081-50-1
(E)-2-(2-isonicotinoylhydrazineylidene)propanoic acid

: [tetrakis(p-fluorobenzyl)bis(pyruvate isonicotinyl hydrazonate)diaquaditin(IV)]

Guidance literature:: With triethylamine; In toluene; Ar, equimol., refluxed for 1 h, triethylamine added, refluxed for 1 h; evapd. (vac.), recrystd. (methanol); elem. anal.;
DOI:10.1002/ejic.200500412

Reference yield: 86.0%

: 2069-76-3
tris(p-fluorobenzyl)tin chloride

: 20781-56-0
N-(2-(propionic acid))salicyloyl hydrazone

: [(p-FC₆H₄CH₂)2Sn(2-HOC₆H₄CON₂C(CH₃)CO₂)]2

Guidance literature:: With Et₃N; In toluene; byproducts: p-FC6H4CH3, (Et3NH)Cl; hydrazone (1 equiv.) and Sn compd. (1 equiv.) were added to toluene; mixt. was stirred under reflux for 1 h; Et3N (1 equiv.) was added; mixt. was refluxed for 1 h; evapd. (vac.); recrystd. (methanol); elem. anal.;
DOI:10.1016/j.jorganchem.2004.12.037