Butanoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (3S)-

Base Information

Chemical Name:Butanoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (3S)-
CAS No.:215444-96-5
Molecular Formula:C21H28O3Si
Molecular Weight:356.537
Hs Code.:
Mol file:215444-96-5.mol

Synonyms:

Suppliers and Price of Butanoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (3S)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Butanoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (3S)-

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of Butanoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (3S)-

There total 3 articles about Butanoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (3S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 53562-86-0
(S)-3-hydroxybutyric acid methyl ester

: 58479-61-1
tert-butylchlorodiphenylsilane

: 215444-96-5
methyl (3S)-3-{[tert-butyl(diphenyl)silyl]oxy}butanoate

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(96)00857-X

Reference yield:

: 105-45-3
acetoacetic acid methyl ester

: 215444-96-5
methyl (3S)-3-{[tert-butyl(diphenyl)silyl]oxy}butanoate

Guidance literature:: Multi-step reaction with 2 steps

1: ruthenium trichloride; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); hydrogen / methanol / 36 h / 25 °C / 77574.3 Torr / Autoclave

2: 1H-imidazole / dichloromethane / 3 h / 0 - 20 °C

With 1H-imidazole; ruthenium trichloride; hydrogen; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); In methanol; dichloromethane; 1: |Noyori Asymmetric Hydrogenation;
DOI:10.1016/j.tet.2015.06.035