Benzyl 2-methylidenebutanoate

Base Information

Chemical Name:Benzyl 2-methylidenebutanoate
CAS No.:219506-75-9
Molecular Formula:C12H14O2
Molecular Weight:190.242
Hs Code.:
European Community (EC) Number:630-741-0
DSSTox Substance ID:DTXSID80584338
Nikkaji Number:J1.062.825C
Wikidata:Q82475986
Mol file:219506-75-9.mol

Synonyms:Benzyl 2-methylidenebutanoate;219506-75-9;Benzyl 2-ethyl acrylate;BENZYL 2-ETHYL ACRYLATE, 99%;Benzyl 2-methylenebutanoate;SCHEMBL1812517;DTXSID80584338

Suppliers and Price of Benzyl 2-methylidenebutanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
BENZYL 2-ETHYL ACRYLATE 95.00%
250MG
$ 856.20

Total 5 raw suppliers

Chemical Property of Benzyl 2-methylidenebutanoate

Chemical Property:

PSA：26.30000
LogP:2.69600
XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:190.099379685
Heavy Atom Count:14
Complexity:202

Purity/Quality:

97% ^*data from raw suppliers

BENZYL 2-ETHYL ACRYLATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi,N
Statements: 36/37/38-51/53
Safety Statements: 26-28-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(=C)C(=O)OCC1=CC=CC=C1

Technology Process of Benzyl 2-methylidenebutanoate

There total 3 articles about Benzyl 2-methylidenebutanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 4390-96-9
2-ethylacryloyl chloride

: 100-51-6,185532-71-2
benzyl alcohol

: 219506-75-9
2-benzyloxycarbonyl-1-butene

Guidance literature:: With triethylamine; In chloroform; at 0 - 30 ℃; for 4h; Heating / reflux;

Reference yield:

: 51951-27-0
2-isopropoxyisoindoline-1,3-dione

: 89295-32-9
2-(ethoxycarbonyl)prop-2-en-1-yl phenyl sulfone

: 219506-75-9
2-benzyloxycarbonyl-1-butene

: 118053-31-9
benzyl 4-methyl-2-methylenepentanoate

Guidance literature:: 2-isopropoxyisoindoline-1,3-dione; With (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; at 20 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

2-(ethoxycarbonyl)prop-2-en-1-yl phenyl sulfone; With phosphorous acid trimethyl ester; In tert-butyl methyl ether; at 20 ℃; for 12h; Overall yield = 75 %; Overall yield = 30.4 mg; Inert atmosphere; Schlenk technique; Irradiation;
DOI:10.1002/chem.201806138