2-Butanone,3-oxo-,(2,4-dinitrophenyl)hydrazone

Base Information

Chemical Name:2-Butanone,3-oxo-,(2,4-dinitrophenyl)hydrazone
CAS No.:2256-00-0
Molecular Formula:C₁₀H₁₀N₄O₅
Molecular Weight:266.213
Hs Code.:2928000090
DSSTox Substance ID:DTXSID90430352
Mol file:2256-00-0.mol

Synonyms:2-Butanone,3-oxo-,(2,4-dinitrophenyl)hydrazone;2256-00-0;Diacetyl 2,4-Dinitrophenylhydrazone;(3E)-3-[(2,4-dinitrophenyl)hydrazinylidene]butan-2-one;(2E)-2,3-Butanedione 2-[(2,4-dinitrophenyl)hydrazone] #;DTXSID90430352;CMMZDRNKABQCMK-IZZDOVSWSA-N;(2E)-2,3-Butanedione 2-[(2,4-dinitrophenyl)hydrazone]

Suppliers and Price of 2-Butanone,3-oxo-,(2,4-dinitrophenyl)hydrazone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Diacetyl2,4-Dinitrophenylhydrazone
100mg
$ 175.00

Total 7 raw suppliers

Chemical Property of 2-Butanone,3-oxo-,(2,4-dinitrophenyl)hydrazone

Chemical Property:

Melting Point:171-174°C
PSA：133.10000
LogP:2.99920
Storage Temp.:Hygroscopic, Refrigerator, under inert atmosphere
Solubility.:Chloroform (Slightly), Methanol (Very Slightly, Heated)
XLogP3:0.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:3
Exact Mass:266.06511943
Heavy Atom Count:19
Complexity:411

Purity/Quality:

99% ^*data from raw suppliers

Diacetyl2,4-Dinitrophenylhydrazone ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])C(=O)C
Isomeric SMILES:C/C(=N\NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])/C(=O)C
Uses Diacetyl 2,4-Dinitrophenylhydrazone is the derivative of 2,4-Dinitrophenylhydrazone (DNPH). Also, it is used in TLC as internal standards. 2,4-Dinitrophenylhydrazone (DNPH) derivative. Also, it is used in TLC as internal standards.

Technology Process of 2-Butanone,3-oxo-,(2,4-dinitrophenyl)hydrazone

There total 3 articles about 2-Butanone,3-oxo-,(2,4-dinitrophenyl)hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: 26487-92-3
3-(triphenylphosphoranylidene)butan-2-one

: 345-12-0
2,4-dinitrophenyldiazonium tetrafluoroborate

: 2256-00-0
2,3-butanedione 2-(2,4-dinitrophenylhydrazone)

Guidance literature:: In acetonitrile; Ambient temperature;

Reference yield:

: 97-02-9
2,4-Dinitroanilin

: 2256-00-0
2,3-butanedione 2-(2,4-dinitrophenylhydrazone)

Guidance literature:: Multi-step reaction with 2 steps

1: 1) conc. H₂SO₄, isopentyl nitrate, 40percent HBF₄ / 1) glacial acetic acid, below 20 deg C

2: 39 percent / acetonitrile / Ambient temperature

With tetrafluoroboric acid; isopentyl nitrate; sulfuric acid; In acetonitrile;

Reference yield:

: 2256-00-0
2,3-butanedione 2-(2,4-dinitrophenylhydrazone)

Guidance literature:: Diacetyl, 2,4-DNPH (gesaett. wss. Lsg.in 2n-HCl), Raumtemp. (neben entspr. Bis-<2,4-Dinitro-phenylhydrazon>;
DOI:10.1021/jo01060a056