13-Oxotetradecanoic acid

Base Information

• Chemical Name: 13-Oxotetradecanoic acid
• CAS No.: 2389-02-8
• Molecular Formula: C14H26O3
• Molecular Weight: 242.359
• Hs Code.: 2918300090
• Mol file: 2389-02-8.mol

Synonyms:CO13;13-keto myristic acid;Tetradecanoic acid,13-oxo;13-Oxo-tetradecansaeure;13-oxo-tetradecanoic acid;13CO-Myristic acid;

Chemical Property of 13-Oxotetradecanoic acid

Chemical Property:

• PSA: 54.37000
• LogP: 3.95110

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 13-Oxotetradecanoic acid

There total 2 articles about 13-Oxotetradecanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-acetyl-2-docosanoyl-tridecanedioic acid diethyl ester → 13-oxotetradecanoic acid (2389-02-8) + n-docosanoic acid (112-85-6) + 13-oxo-tetratriacontanoic acid (122335-19-7)

Guidance literature:

Anschliessend mit verd. H₂SO₄ und Na₂CO_3.;

Reference yield:

n-tetradecanoic acid (544-63-8) + trifluoroacetic acid (76-05-1) → 13-oxotetradecanoic acid (2389-02-8) + 9-oxo-tetradecanoic acid (71173-32-5) + 10-oxotetradecanoic acid (675-95-6) + 8-Oxotetradecanoic acid (39747-88-1)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In dichloromethane; Yield given. Further byproducts given. Yields of byproduct given;

Reference yield: 49.0%

13-oxotetradecanoic acid (2389-02-8) → tridec-12-en-2-one (60437-21-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; 3,3',5,5'-tetra(tert-butyl)biphenyl-2,2'-diol; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In neat (no solvent); at 132 ℃; for 3h; Inert atmosphere;

DOI:10.1002/adsc.201301109

upstream raw materials:

n-tetradecanoic acid

trifluoroacetic acid

Downstream raw materials:

brassylic acid

13-Hydroxymyristic acid

tridec-12-en-2-one

Refernces