9H-Carbazole, 3,6-dibromo-9-(4-nitrophenyl)-

Base Information

• Chemical Name: 9H-Carbazole, 3,6-dibromo-9-(4-nitrophenyl)-
• CAS No.: 255829-24-4
• Molecular Formula: C18H10Br2N2O2
• Molecular Weight: 446.098
• DSSTox Substance ID: DTXSID90442298
• Nikkaji Number: J2.907.823H
• Mol file: 255829-24-4.mol

Synonyms:3,6-DIBROMO-9-(4-NITROPHENYL)-9H-CARBAZOLE;9H-Carbazole, 3,6-dibromo-9-(4-nitrophenyl)-;255829-24-4;SCHEMBL999612;DTXSID90442298;STL196876;AKOS025270024

Chemical Property of 9H-Carbazole, 3,6-dibromo-9-(4-nitrophenyl)-

Chemical Property:

• XLogP3: 6.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 445.90885
• Heavy Atom Count: 24
• Complexity: 452

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1N2C3=C(C=C(C=C3)Br)C4=C2C=CC(=C4)Br)[N+](=O)[O-]

Technology Process of 9H-Carbazole, 3,6-dibromo-9-(4-nitrophenyl)-

There total 5 articles about 9H-Carbazole, 3,6-dibromo-9-(4-nitrophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3,6-dibromo-9H-carbazole (6825-20-3) + 4-Fluoronitrobenzene (350-46-9,178603-76-4) → 3,6-dibromo-9-(4-nitrophenyl)-9H-carbazole (255829-24-4)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide;

Reference yield: 87.0%

9-(4-nitrophenyl)-9H-carbazole (16982-76-6) → 3,6-dibromo-9-(4-nitrophenyl)-9H-carbazole (255829-24-4)

Guidance literature:

With bromine; In chloroform; at 20 ℃; for 12h;

DOI:10.1021/jo991167h

Reference yield:

9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 3,6-dibromo-9-(4-nitrophenyl)-9H-carbazole (255829-24-4)

Guidance literature:

Multi-step reaction with 2 steps

1: N-Bromosuccinimide / N,N-dimethyl-formamide

2: cesium fluoride / dimethyl sulfoxide

With N-Bromosuccinimide; cesium fluoride; In dimethyl sulfoxide; N,N-dimethyl-formamide;

DOI:10.1039/c5tc03860j

upstream raw materials:

9-(4-nitrophenyl)-9H-carbazole

9H-carbazole

nitrobenzene

3,6-dibromo-9H-carbazole

Downstream raw materials:

3,6-(di-9H-carbazol-9-yl)-9-(4-nitrophenyl)-9H-carbazole

4-(3,6-(di-9H-carbazol-9-yl)-9H-carbazol-9-yl)-4',4''-dibromotriphenylamine

4-(3,6-dibromo-9H-carbazol-9-yl)aniline