1-Acetyl-2,2-dichloro-1-methylcyclopropane

Base Information

• Chemical Name: 1-Acetyl-2,2-dichloro-1-methylcyclopropane
• CAS No.: 2568-72-1
• Molecular Formula: C₆H₈Cl₂O
• Molecular Weight: 167.035
• Mol file: 2568-72-1.mol

Synonyms:(+-)-1-Acetyl-2,2-dichlor-1-methyl-cyclopropan;1-(2,2-Dichlor-1-methyl-cyclopropyl)-aethanon;Ethanone,1-(2,2-dichloro-1-methylcyclopropyl);1-(2,2-dichloro-1-methyl-cyclopropyl)-ethanone;1-Acetyl-2,2-dichloro-1-methylcyclopropane;

Chemical Property of 1-Acetyl-2,2-dichloro-1-methylcyclopropane

Chemical Property:

• PSA: 17.07000
• LogP: 2.15930

Purity/Quality:

99% ^*data from raw suppliers

1-Acetyl-2,2-dichloro-1-methylcyclopropane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Acetyl-2,2-dichloro-1-methylcyclopropane

There total 4 articles about 1-Acetyl-2,2-dichloro-1-methylcyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

1,1-dichloro-2-methyl-2-(prop-1-en-2-yl)cyclopropane (17725-80-3) → (+/-)-1-Acetyl-2,2-dichlor-1-methyl-cyclopropan (2568-72-1)

Guidance literature:

1,1-dichloro-2-methyl-2-(prop-1-en-2-yl)cyclopropane; With oxygen; ozone; acetic acid; In dichloromethane; at -65 ℃;

With semicarbazide hydrochloride; In dichloromethane; at -65 - 20 ℃;

DOI:10.1134/S1070428018030028

Reference yield:

(+/-)-1-Aethinyl-2,2-dichlor-1-methyl-cyclopropan (2566-03-2) → (+/-)-1-Acetyl-2,2-dichlor-1-methyl-cyclopropan (2568-72-1)

Guidance literature:

With mercury(II) sulfate; In methanol;

Reference yield:

2-methylbut-1-en-3-yne (78-80-8) → (+/-)-1-Acetyl-2,2-dichlor-1-methyl-cyclopropan (2568-72-1)

Guidance literature:

Multi-step reaction with 2 steps

1: KOtBu

2: HgSO₄ / methanol

With potassium tert-butylate; mercury(II) sulfate; In methanol;

upstream raw materials:

(+/-)-1-Aethinyl-2,2-dichlor-1-methyl-cyclopropan

2-methylbut-1-en-3-yne

1,1-dichloro-2-methyl-2-(prop-1-en-2-yl)cyclopropane